Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
Reads0
Chats0
TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
More filters
Journal ArticleDOI
Single- or Poly-Crystalline Ni-Rich Layered Cathode, Sulfide or Halide Solid Electrolyte: Which Will be the Winners for All-Solid-State Batteries?
Yoonjae Han,Yoonjae Han,Sung Hoo Jung,Hiram Kwak,Hiram Kwak,Seunggoo Jun,Hunho H. Kwak,Jong Hoon Lee,Seung-Tae Hong,Yoon Seok Jung +9 more
Journal ArticleDOI
Recent progress on electrolyte additives for stable lithium metal anode
TL;DR: Li et al. as mentioned in this paper reviewed the recent progress of electrolyte additives in protecting Li anode and summarized the existing challenges of additives and proposed some prospects combined with the practice. And they introduced several main mechanism of Li dendrite growth.
Journal ArticleDOI
Realizing high-power and high-capacity zinc/sodium metal anodes through interfacial chemistry regulation
TL;DR: Zhang et al. as discussed by the authors constructed electrically conductive and zincophilic tin coating on separator to suppress dendrite initiation and eliminate the inevitably formed dendrites, achieving superior zinc morphologies and superior cycling stability at simultaneous high current densities and large cycling capacities.
Journal ArticleDOI
Suppressing dendrite growth by a functional electrolyte additive for robust Li metal anodes
Gang Wang,Xunhui Xiong,Dong Xie,Fu Xiangxiang,Xiangdong Ma,Youpeng Li,Yanzhen Liu,Zhang Lin,Chenghao Yang,Meilin Liu +9 more
TL;DR: In this article, an optimal amount of lithium iodide (LiI) as a functional additive in ether-based electrolyte for dendrite-free Li deposition was proposed, which induced the electrolyte polymerization to in-situ form a robust solid electrolyte interphase (SEI) layer enriched with elastic oligomer on Li surface.
Journal ArticleDOI
ZnO/carbon framework derived from metal-organic frameworks as a stable host for lithium metal anodes
Leying Wang,Xiayu Zhu,Yuepeng Guan,Jinliang Zhang,Fei Ai,Wenfeng Zhang,Yu Xiang,Vijayan Srinivasapriyan,Guodong Li,Yaqin Huang,Gaoping Cao,Yusheng Yang,Hao Zhang +12 more
TL;DR: In this paper, the authors demonstrate a promising metallic lithium anode design by infusing molten lithium into a ZnO/carbon framework, which is obtained by pyrolysis of a typical metal-organic framework (MOF).
References
More filters
Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.