Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Metal-organic framework nanosheets-guided uniform lithium deposition for metallic lithium batteries
Zhanguo Jiang,Tiefeng Liu,Lijing Yan,Jie Liu,Feifei Dong,Min Ling,Chengdu Liang,Zhan Lin,Zhan Lin +8 more
TL;DR: In this article, the metal-organic framework (MOF) nanosheets modified electrodes are designed to inhabit Li dendrite growth with improved electrochemical performance, which facilitates well-distributed homogeneous Li ionic flux.
Journal ArticleDOI
Lithiated zinc oxide nanorod arrays on copper current collectors for robust Li metal anodes
Gang Wang,Xunhui Xiong,Pinjuan Zou,Fu Xiangxiang,Zhihua Lin,Youpeng Li,Yanzhen Liu,Chenghao Yang,Meilin Liu +8 more
TL;DR: In this paper, a Cu foil decorated by a lithiated ZnO nanorod array is designed as an advanced current collector, in which the aligned LiZn/Li2O array skeleton not only regulates Li plating/stripping behavior along nanorods, but also reduces the local current density as well as supplies buffers for alleviating the volume change during cycling.
Journal ArticleDOI
Facile Patterning of Laser‐Induced Graphene with Tailored Li Nucleation Kinetics for Stable Lithium‐Metal Batteries
Yi Jingsi,Chen Jiahua,Zheng Yang,Yang Dai,Weimin Li,Jiang Cui,Francesco Ciucci,Ziheng Lu,Chunlei Yang +8 more
Journal ArticleDOI
3D Coral-like LLZO/PVDF Composite Electrolytes with Enhanced Ionic Conductivity and Mechanical Flexibility for Solid-State Lithium Batteries.
TL;DR: 3D interconnected garnet frameworks are used as a 3D active nanofiller in a poly(vinylidene difluoride) polymer matrix and demonstrate the superiority of 3D interconnected Garnet frameworks in developing CPEs with excellent electrochemical and mechanical properties.
Journal ArticleDOI
Modeling and theoretical design of next-generation lithium metal batteries
TL;DR: In this article, a review of theoretical studies on sulfur cathodes, oxygen, lithium metal anodes, and solid-state electrolytes (SSEs) of rechargeable lithium metal batteries is presented.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.