Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Performance and cost of materials for lithium-based rechargeable automotive batteries
TL;DR: In this article, the state-of-the-art advances in active materials, electrolytes and cell chemistries for automotive batteries are surveyed, along with an assessment of the potential to fulfil the ambitious targets of electric vehicle propulsion.
Journal ArticleDOI
Applications of 2D MXenes in energy conversion and storage systems
Jinbo Pang,Rafael G. Mendes,Rafael G. Mendes,Alicja Bachmatiuk,Alicja Bachmatiuk,Alicja Bachmatiuk,Liang Zhao,Huy Q. Ta,Thomas Gemming,Hong Liu,Hong Liu,Zhongfan Liu,Zhongfan Liu,Mark H. Rümmeli,Mark H. Rümmeli,Mark H. Rümmeli +15 more
TL;DR: The potential of MXenes for the photocatalytic degradation of organic pollutants in water, such as dye waste, is addressed, along with their promise as catalysts for ammonium synthesis from nitrogen.
Journal ArticleDOI
Advancing Lithium Metal Batteries
Bin Liu,Ji-Guang Zhang,Wu Xu +2 more
TL;DR: Li metal anodes are well known to be one of the most promising anodes due to their ultra-high capacity (3,860 mAh g −1 ) and the very low standard negative electrochemical potential (−3.040 V) as discussed by the authors.
Journal ArticleDOI
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
Journal ArticleDOI
Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry
TL;DR: The current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.
References
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Journal ArticleDOI
Insights into degradation of metallic lithium electrodes protected by a bilayer solid electrolyte based on aluminium substituted lithium lanthanum titanate in lithium-air batteries
TL;DR: In this paper, a protected Li electrode (PLE) composed of Li metal covered with a bilayer lithium phosphorous oxynitride (LiPON)/aluminium substituted lithium lanthanum titanate (A-LLTO) solid electrolyte was suggested.
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Analysis of composite electrolytes with sintered reinforcement structure for energy storage applications
Sergiy Kalnaus,Wyatt E. Tenhaeff,Jeff Sakamoto,Adrian S. Sabau,Claus Daniel,Claus Daniel,Nancy J. Dudney +6 more
TL;DR: In this paper, the mechanical ability of the membrane to block lithium dendrites was assessed based on a stability criterion, which depends on the computed effective stiffness, and the minimum size of the inter-particle connections necessary to provide mechanical stability without losing the enhancement in conductivity was 0.05 times the mean particle radius.
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Lithium bis(fluorosulfonyl)imide based low ethylene carbonate content electrolyte with unusual solvation state
Satoshi Uchida,Masashi Ishikawa +1 more
TL;DR: Li et al. as mentioned in this paper proposed a lithium bis(fluorosulfonyl)imide (LiFSI)-based low ethylene carbonate (EC) content electrolyte as a new electrolyte.
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Enhanced cycling performance of lithium metal secondary batteries with succinic anhydride as an electrolyte additive
Gi-Beom Han,Je-Nam Lee,Dong Jin Lee,Hongkyung Lee,Jongchan Song,Hyewon Lee,Myung-Hyun Ryou,Jung-Ki Park,Yong Min Lee +8 more
TL;DR: In this article, the effect of succinic anhydride (SA) as an electrolyte additive on the cycling performance of Li electrode is discussed, and the authors show that the Li electrode thickness increases only about 45μm (from 100 to 145μm) after 40 cycles, whereas an increase of about 210μm occurs without SA.
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Integrated reduced graphene oxide multilayer/Li composite anode for rechargeable lithium metal batteries
TL;DR: In this article, an integrated reduced graphene oxide (rGO) multilayer/Li composite electrode, in which filtration-synthesized free-standing rGO film acts as a conductive support for the strong anchoring of Li metal, is presented.