Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Electric car battery: An overview on global demand, recycling and future approaches towards sustainability.
Lívia Salles Martins,Lucas Fonseca Guimarães,Amilton Barbosa Botelho Junior,Jorge Alberto Soares Tenório,Denise Crocce Romano Espinosa +4 more
TL;DR: In this article, an overview of current and future vehicles used worldwide is presented, where the authors describe the importance and benefits of recycling as regards the supply of critical metals and future trends towards a circular economy.
Journal ArticleDOI
Recent progress in developing Li2S cathodes for Li–S batteries
TL;DR: Li2S-based rechargeable batteries have been investigated as the cathode material for next-generation rechargeable battery as discussed by the authors, which offers the prospect of lithium-metal-free anodes and will also alleviate the volume expansion issues otherwise occurred in the sulfur cathode.
Journal ArticleDOI
The rational design of biomass-derived carbon materials towards next-generation energy storage: A review
Zongyhuan Zhu,Zhen Xu +1 more
TL;DR: In this article, the most updated research progress in the synthesis of biomass-derived carbon material for developing high-performance supercapacitors, rechargeable batteries and fuel cells are critically reviewed and summarized.
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Perspective on the critical role of interface for advanced batteries
Journal ArticleDOI
Polymorph Evolution Mechanisms and Regulation Strategies of Lithium Metal Anode under Multiphysical Fields.
Peichao Zou,Peichao Zou,Yiming Sui,Houchao Zhan,Chunyang Wang,Huolin L. Xin,Hui-Ming Cheng,Hui-Ming Cheng,Feiyu Kang,Cheng Yang +9 more
TL;DR: In this article, the authors provide a clear picture and in-depth discussion on the classification and initiation/growth mechanisms of polymorphous Li from the new perspective of multiphysical fields, particularly for irregular Li patterns.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.