Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
Reads0
Chats0
TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
More filters
Journal ArticleDOI
Stabilization Perspective on Metal Anodes for Aqueous Batteries
Journal ArticleDOI
Recent Advances in Silicon-Based Electrodes: From Fundamental Research toward Practical Applications
Mingzheng Ge,Chunyan Cao,Gill M. Biesold,Christopher D. Sewell,Shu-Meng Hao,Jianying Huang,Wei Zhang,Yuekun Lai,Zhiqun Lin +8 more
TL;DR: The state-of-the-art developments made in the rational design of Si-based electrodes and their progression toward practical application are presented in this article, where a comprehensive overview of fundamental electrochemistry and selected critical challenges are given, including their large volume expansion, unstable solid electrolyte interface (SEI) growth, low initial Coulombic efficiency, low areal capacity, and safety issues.
Journal ArticleDOI
Strategies towards enabling lithium metal in batteries: interphases and electrodes
Birger Horstmann,Jiayan Shi,Rachid Amine,Martin Werres,Xin He,Hao Jia,Florian Hausen,Isidora Cekic-Laskovic,Simon Wiemers-Meyer,Jeffrey Lopez,Diego E. Galvez-Aranda,Florian Baakes,Dominic Bresser,Chi-Cheung Su,Yaobin Xu,Wu Xu,Peter Jakes,Rüdiger-A. Eichel,Egbert Figgemeier,Ulrike Krewer,Jorge M. Seminario,Perla B. Balbuena,Chongmin Wang,Stefano Passerini,Yang Shao-Horn,Martin Winter,Martin Winter,Khalil Amine,Khalil Amine,Robert Kostecki,Arnulf Latz +30 more
TL;DR: In this paper, the authors discuss how experimental and theoretical insights can provide possible pathways for reversible cycling of two-dimensional lithium metal and discuss improvements in the understanding of lithium metal nucleation, deposition, and stripping on the nanoscale.
References
More filters
Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.