Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Performance and cost of materials for lithium-based rechargeable automotive batteries
TL;DR: In this article, the state-of-the-art advances in active materials, electrolytes and cell chemistries for automotive batteries are surveyed, along with an assessment of the potential to fulfil the ambitious targets of electric vehicle propulsion.
Journal ArticleDOI
Applications of 2D MXenes in energy conversion and storage systems
Jinbo Pang,Rafael G. Mendes,Rafael G. Mendes,Alicja Bachmatiuk,Alicja Bachmatiuk,Alicja Bachmatiuk,Liang Zhao,Huy Q. Ta,Thomas Gemming,Hong Liu,Hong Liu,Zhongfan Liu,Zhongfan Liu,Mark H. Rümmeli,Mark H. Rümmeli,Mark H. Rümmeli +15 more
TL;DR: The potential of MXenes for the photocatalytic degradation of organic pollutants in water, such as dye waste, is addressed, along with their promise as catalysts for ammonium synthesis from nitrogen.
Journal ArticleDOI
Advancing Lithium Metal Batteries
Bin Liu,Ji-Guang Zhang,Wu Xu +2 more
TL;DR: Li metal anodes are well known to be one of the most promising anodes due to their ultra-high capacity (3,860 mAh g −1 ) and the very low standard negative electrochemical potential (−3.040 V) as discussed by the authors.
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Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
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Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry
TL;DR: The current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.
References
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Journal ArticleDOI
Surface characterization of emulsified lithium powder electrode
TL;DR: In this article, the surface modification of Li powder was attempted in order to enhance the electrochemical properties of the electrodes used in rechargeable batteries, and two-electrode cells were prepared for the purpose of impedance analysis and scanning electron microscope (SEM) observation.
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Effect of Alkali and Alkaline Earth Metal Salts on Suppression of Lithium Dendrites
Johanna K. Goodman,Paul A. Kohl +1 more
TL;DR: In this paper, the effect of alkali and alkaline earth metal ions on the morphology of electrodeposited lithium metal has been studied, and it was shown that the presence of alkaline metal ions at 0.05 M concentration significantly reduced the occurrence of dendrites.
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Stabilizing effect of 2-(triphenylphosphoranylidene) succinic anhydride as electrolyte additive on the lithium metal of lithium metal secondary batteries
TL;DR: In this paper, 2-(triphenylphosphoranylidene) succinic anhydride (TPSA) was used as a surface-stabilizing electrolyte additive for improving the cycle performance of Li metal secondary batteries.
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Strategies of constructing stable and high sulfur loading cathodes based on the blade-casting technique
TL;DR: In this paper, a micro-nano-structured CS@CTAB/ABS + CNTS electrode with high sulfur content of 76 wt% and a high sulfur mass loading of 6.7-11.1 mg cm−2 was constructed for application in Li-S batteries via the blade-casting technique.
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Prospects for Dendrite-Free Cycling of Li Metal Batteries
Qing Chen,Ke Geng,Karl Sieradzki +2 more