Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Performance and cost of materials for lithium-based rechargeable automotive batteries
TL;DR: In this article, the state-of-the-art advances in active materials, electrolytes and cell chemistries for automotive batteries are surveyed, along with an assessment of the potential to fulfil the ambitious targets of electric vehicle propulsion.
Journal ArticleDOI
Applications of 2D MXenes in energy conversion and storage systems
Jinbo Pang,Rafael G. Mendes,Rafael G. Mendes,Alicja Bachmatiuk,Alicja Bachmatiuk,Alicja Bachmatiuk,Liang Zhao,Huy Q. Ta,Thomas Gemming,Hong Liu,Hong Liu,Zhongfan Liu,Zhongfan Liu,Mark H. Rümmeli,Mark H. Rümmeli,Mark H. Rümmeli +15 more
TL;DR: The potential of MXenes for the photocatalytic degradation of organic pollutants in water, such as dye waste, is addressed, along with their promise as catalysts for ammonium synthesis from nitrogen.
Journal ArticleDOI
Advancing Lithium Metal Batteries
Bin Liu,Ji-Guang Zhang,Wu Xu +2 more
TL;DR: Li metal anodes are well known to be one of the most promising anodes due to their ultra-high capacity (3,860 mAh g −1 ) and the very low standard negative electrochemical potential (−3.040 V) as discussed by the authors.
Journal ArticleDOI
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
Journal ArticleDOI
Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry
TL;DR: The current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.
References
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Journal ArticleDOI
Microsized Sn as Advanced Anodes in Glyme-Based Electrolyte for Na-Ion Batteries
Biao Zhang,Biao Zhang,Gwena�lle Rousse,Dominique Foix,Dominique Foix,Romain Dugas,Romain Dugas,Daniel Alves Dalla Corte,Daniel Alves Dalla Corte,Jean-Marie Tarascon +9 more
TL;DR: Microsized Sn presents stable cyclic performance in a glyme-based electrolyte, which brings 19% increase in energy density of Sn/Na3 V2 (PO4 )3 cells as compared to the cells using a hard carbon anode.
Journal ArticleDOI
Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes
Hongfa Xiang,Hongfa Xiang,Pengcheng Shi,Priyanka Bhattacharya,Xilin Chen,Donghai Mei,Mark E. Bowden,Jianming Zheng,Ji-Guang Zhang,Wu Xu +9 more
TL;DR: In this paper, the authors demonstrate the rapid charging capability of Li||LiNi0.8Co0.15Al0.05O2 (NCA) cells with a dual-salt electrolyte of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and lithium bis (oxalato)borate (LiBOB) in a carbonate solvent mixture.
Journal ArticleDOI
Nanostructured Electrolytes for Stable Lithium Electrodeposition in Secondary Batteries
TL;DR: The range of options for designing electrolytes and separators that stabilize electrodeposition is now substantially broader than one might imagine from previous literature accounts, and a promising finding is that simple film-forming halide salt additives in a conventional liquid electrolyte can substantially extend the lifetime and safety of LMBs.
Journal ArticleDOI
Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems
TL;DR: In this paper, an overview of the interfacial behaviors between lithium ion (Li-ion) conductors and cathode/anode materials is presented. But, the integration of highly conductive solid electrolytes into the whole system is still very challenging mainly due to the high impedance existing at different interfaces throughout the battery structure.
Journal ArticleDOI
Stable Artificial Solid Electrolyte Interphases for Lithium Batteries
TL;DR: In this paper, the chemistry and interfacial properties of artificial SEI films created by in situ reaction of a strong Lewis acid AlI3, Li metal, and aprotic liquid electrolytes are investigated.