Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Review of Emerging Concepts in SEI Analysis and Artificial SEI Membranes for Lithium, Sodium, and Potassium Metal Battery Anodes
Journal ArticleDOI
Nanowires for Electrochemical Energy Storage.
TL;DR: This review gives a systematic overview of the state-of-the-art research progress on nanowires for electrochemical energy storage, from rational design and synthesis, in situ structural characterizations, to several important applications in energy storage including lithium-ion batteries, lithium-sulfur batteries, sodium-ION batteries, and supercapacitors.
Journal ArticleDOI
A review on energy chemistry of fast-charging anodes.
Wenlong Cai,Yu-Xing Yao,Gao-Long Zhu,Gao-Long Zhu,Chong Yan,Li-Li Jiang,Chuanxin He,Jia-Qi Huang,Qiang Zhang +8 more
TL;DR: The fundamentals, challenges, and solutions to enable graphite anodes that are capable of high-rate charging are summarized and some promising strategies proposed during the past few years are highlighted so as to outline current trends and future perspectives in this field.
Journal ArticleDOI
Lithiophilic LiC6 Layers on Carbon Hosts Enabling Stable Li Metal Anode in Working Batteries.
Peng Shi,Tao Li,Rui Zhang,Xin Shen,Xin-Bing Cheng,Rui Xu,Jia-Qi Huang,Xiao-Ru Chen,He Liu,Qiang Zhang +9 more
TL;DR: It is demonstrated that the as-obtained Li/CF composite anode with lithiophilic LiC6 layers can effectively alleviate volume expansion and hinder dendritic and powdery morphology of Li deposits.
Journal ArticleDOI
Guiding Uniform Li Plating/Stripping through Lithium-Aluminum Alloying Medium for Long-Life Li Metal Batteries.
Huan Ye,Huan Ye,Zijian Zheng,Hu-Rong Yao,Shun-Chang Liu,Tong-Tong Zuo,Xiongwei Wu,Ya-Xia Yin,Nianwu Li,Jiangjiang Gu,Fei-Fei Cao,Yu-Guo Guo +11 more
TL;DR: A lithiophilic binary lithium-aluminum alloy layer was utilized to guide the uniform metallic Li nucleation and growth, free from the formation of dendrites, enabling long-term stability in a Li|Li symmetric cell.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.