Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Performance and cost of materials for lithium-based rechargeable automotive batteries
TL;DR: In this article, the state-of-the-art advances in active materials, electrolytes and cell chemistries for automotive batteries are surveyed, along with an assessment of the potential to fulfil the ambitious targets of electric vehicle propulsion.
Journal ArticleDOI
Applications of 2D MXenes in energy conversion and storage systems
Jinbo Pang,Rafael G. Mendes,Rafael G. Mendes,Alicja Bachmatiuk,Alicja Bachmatiuk,Alicja Bachmatiuk,Liang Zhao,Huy Q. Ta,Thomas Gemming,Hong Liu,Hong Liu,Zhongfan Liu,Zhongfan Liu,Mark H. Rümmeli,Mark H. Rümmeli,Mark H. Rümmeli +15 more
TL;DR: The potential of MXenes for the photocatalytic degradation of organic pollutants in water, such as dye waste, is addressed, along with their promise as catalysts for ammonium synthesis from nitrogen.
Journal ArticleDOI
Advancing Lithium Metal Batteries
Bin Liu,Ji-Guang Zhang,Wu Xu +2 more
TL;DR: Li metal anodes are well known to be one of the most promising anodes due to their ultra-high capacity (3,860 mAh g −1 ) and the very low standard negative electrochemical potential (−3.040 V) as discussed by the authors.
Journal ArticleDOI
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
Journal ArticleDOI
Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry
TL;DR: The current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.
References
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Journal ArticleDOI
Single Lithium-Ion Conducting Polymer Electrolytes Based on a Super-Delocalized Polyanion.
Qiang Ma,Heng Zhang,Chongwang Zhou,Liping Zheng,Pengfei Cheng,Jin Nie,Wenfang Feng,Yong-Sheng Hu,Hong Li,Xuejie Huang,Liquan Chen,Michel Armand,Zhibin Zhou +12 more
TL;DR: Outstanding properties of the LiPSsTFSI/PEO blended polymer electrolyte would make it promising as solid polymer electrolytes for Li batteries.
Journal ArticleDOI
Mechanical Surface Modification of Lithium Metal: Towards Improved Li Metal Anode Performance by Directed Li Plating
TL;DR: In this paper, the effect of mechanical surface modification on the performance of Li metal foil electrodes is systematically investigated, and the applied micro-needle surface treatment technique for Li metal has various advantages.
Journal ArticleDOI
Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells
TL;DR: In this paper, the authors present a model of solvent diffusion describing the growth of solid-electrolyte interfaces (SEIs) in Li-ion cells incorporating carbon anodes, and use it to estimate SEI thickness and extract solvent diffusivity values from the capacity loss data.
Journal ArticleDOI
Solid-State Lithium–Sulfur Batteries Operated at 37 °C with Composites of Nanostructured Li7La3Zr2O12/Carbon Foam and Polymer
Xinyong Tao,Xinyong Tao,Yayuan Liu,Wei Liu,Guangmin Zhou,Jie Zhao,Dingchang Lin,Chenxi Zu,Ouwei Sheng,Zhang Wenkui,Hyun-Wook Lee,Yi Cui,Yi Cui +12 more
TL;DR: The facile synthesis of Al3+/Nb5+ codoped cubic Li7La3Zr2O12 (LLZO) nanoparticles and LLZO nanoparticle-decorated porous carbon foam and solid-state Li-S batteries exhibit high Coulombic efficiency and show remarkably stable cycling performance.
Journal ArticleDOI
Stabilizing lithium metal using ionic liquids for long-lived batteries
TL;DR: In this paper, a tailored solid-electrolyte interphase is prepared using a variety of electrolytes based on the N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide room temperature ionic liquid containing lithium salts.