Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Phosphonium Bromides Regulating Solid Electrolyte Interphase Components and Optimizing Solvation Sheath Structure for Suppressing Lithium Dendrite Growth
Shihan Qi,Jian He,Jiandong Liu,Huaping Wang,Mingguang Wu,Fang Li,Daxiong Wu,Xin Li,Jianmin Ma +8 more
Journal ArticleDOI
Atomic layer deposition assisted superassembly of ultrathin ZnO layer decorated hierarchical Cu foam for stable lithium metal anode
Runhao Zhang,Runhao Zhang,Yong Li,Li Qiao,Dongwei Li,Jianlin Deng,Junjie Zhou,Lei Xie,Yue Hou,Tao Wang,Tian Wei,Cao Jinchao,Fengli Cheng,Yang Bo,Kang Liang,Pu Chen,Biao Kong +16 more
TL;DR: Li et al. as mentioned in this paper developed a super-assembled surface-modified lipophilic thin ZnO layer by atomic layer deposition (ALD) and multi-level Cu nanofibers (MCN) on a Cu foam (ZnO-MCNCF) as an advanced Li metal anode host.
Journal ArticleDOI
Advanced characterization techniques for solid state lithium battery research
TL;DR: This review presents a comprehensive overview of recent advances in these three characterization techniques in solid state battery research, and some perspectives of the future evolution of the techniques are presented.
Journal ArticleDOI
Solid-state lithium–sulfur batteries: Advances, challenges and perspectives
Bing Ding,Bing Ding,Jie Wang,Zengjie Fan,Shuang Chen,Qingyang Lin,Xiangjun Lu,Hui Dou,Ashok Kumar Nanjundan,Gleb Yushin,Xiaogang Zhang,Yusuke Yamauchi,Yusuke Yamauchi,Yusuke Yamauchi +13 more
TL;DR: In this article, the mechanisms of Li ion transport and the basic requirements of solid-state electrolytes are discussed, as well as the remaining challenges and plausible solutions, including improved designs and compositions of electrode materials, solid state electrolytes and the electrode/electrolyte interfaces.
Lithium Trapping in Alloy Forming Electrodes and Current Collectors for Lithium Based Batteries
TL;DR: The next generation of lithium based batteries can be expected to be based on lithium alloy forming anode materials which can store up to ten times more charge than the currently used graphite anod as mentioned in this paper.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.