Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Recent progress of composite solid polymer electrolytes for all-solid-state lithium metal batteries
Qingjiang Yu,Jiang Kecheng,Cuiling Yu,Chen Xianjin,Zhang Chuanjian,Yao Yi,Jiang Bin,Long Huijin +7 more
TL;DR: In this paper, composite solid polymer electrolytes (CSPEs) derived from the incorporation of inorganic fillers into Solid Polymer Electrodes (SPEs), which exhibit higher ionic conductivity, better mechanical strength, and superior thermal/electrochemical stability compared to the single-component SPEs, can significantly promote the electrochemical performance of ASSSLBs.
Journal ArticleDOI
Engineering nanoreactors for metal–chalcogen batteries
Yash Boyjoo,Haodong Shi,Haodong Shi,Qiang Tian,Shaomin Liu,Ji Liang,Zhong-Shuai Wu,Zhong-Shuai Wu,Mietek Jaroniec,Jian Liu,Jian Liu,Jian Liu +11 more
TL;DR: In this paper, the main functions of metal-chalcogen batteries (MCBs) and how they can be imparted upon the electrode nanostructures via nanoreactor design and engineering are discussed.
Journal ArticleDOI
A Salt‐in‐Metal Anode: Stabilizing the Solid Electrolyte Interphase to Enable Prolonged Battery Cycling
Lin Fu,Xiancheng Wang,Li Wang,Mintao Wan,Yuanjian Li,Zhao Cai,Yuchen Tan,Guocheng Li,Renming Zhan,Zhi Wei Seh,Yongming Sun +10 more
Journal ArticleDOI
Large-scale synthesis of high-quality lithium-graphite hybrid anodes for mass-controllable and cycling-stable lithium metal batteries
TL;DR: In this paper, a large-scale fabrication of lithium−graphite hybrid (LGH) anodes through a facile one-step stirring molten process is reported, which can effectively reduce local current density during stripping/plating process, thus mitigating dendrite formation and stabilizing interface.
Journal ArticleDOI
A High-Performance Lithium Metal Battery with Ion-Selective Nanofluidic Transport in a Conjugated Microporous Polymer Protective Layer
Kun Zhang,Kun Zhang,Wei Liu,Yuliang Gao,Xiaowei Wang,Zhongxin Chen,Ruiqi Ning,Wei Yu,Runlai Li,Li Li,Xing Li,Kai Yuan,Li Ma,Nan Li,Chao Shen,Wei Huang,Keyu Xie,Kian Ping Loh +17 more
TL;DR: A solution-processable conjugated microporous thermosetting polymer (CMP) is developed that is readily amenable to solution-processing and spray coating, rendering it highly applicable to continuous roll-to-roll lithium metal treatment processes.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.