Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Polymer-Based Solid Electrolytes: Material Selection, Design, and Application
Journal ArticleDOI
Lithium–Magnesium Alloy as a Stable Anode for Lithium–Sulfur Battery
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Insight on Organic Molecules in Aqueous Zn‐Ion Batteries with an Emphasis on the Zn Anode Regulation
Donghong Wang,Qiang Li,Yuwei Zhao,Hu Hong,Hongfei Li,Zhaodong Huang,Guojin Liang,Qi Yang,Chunyi Zhi +8 more
TL;DR: In this article , the role of organic molecules in rechargeable rechargeable aqueous rechargeable ZIBs was investigated and several designed strategies were proposed for further exploration of high performance rechargeable ion batteries through incorporating appropriate organic molecule in the electrolytes.
Journal ArticleDOI
A 3D Lithiophilic Mo 2 N-Modified Carbon Nanofiber Architecture for Dendrite-Free Lithium-Metal Anodes in a Full Cell
TL;DR: A new 3D framework configured with Mo2 N-mofidied carbon nanofiber (CNF) architecture is established as a Li host via a facile fabrication method, facilitating a dendrite-free morphology with greatly alleviated volume expansion and delivering a significantly improved Coulombic efficiency.
Journal ArticleDOI
High-areal-capacity all-solid-state lithium batteries enabled by rational design of fast ion transport channels in vertically-aligned composite polymer electrodes
Xiaofei Yang,Qian Sun,Changtai Zhao,Xuejie Gao,Keegan R. Adair,Yulong Liu,Jing Luo,Xiaoting Lin,Jianneng Liang,Huan Huang,Li Zhang,Rong Yang,Shigang Lu,Ruying Li,Xueliang Sun +14 more
TL;DR: Li et al. as discussed by the authors combined a glass fiber (GF)-reinforced composite polymer electrolyte based on poly(ethylene oxide) to suppress Li dendrite growth with a freeze-casted vertically-aligned (VL) electrode to facilitate Li+ transport in the high loading cathode.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.