Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
Reads0
Chats0
TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
More filters
Journal ArticleDOI
Functional and stability orientation synthesis of materials and structures in aprotic Li–O2 batteries
TL;DR: This review provides insights on the present understanding of the discharge/charge mechanism of such a battery and establishes a correlation between the specific materials/structures of the battery modules and their functionality/stability within the recent progress in electrodes, electrolytes and redox mediators.
Journal ArticleDOI
Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries
TL;DR: In this paper, anion regulation in the solvation sheath for constructing stable solid electrolyte interphases (SEI) on the Li metal anode is rarely touched, and the authors provide fresh insight into the interrelation among various anions on regulating the Solvation Sheath of Li ions.
Journal ArticleDOI
Dendrites in Lithium Metal Anodes: Suppression, Regulation, and Elimination
TL;DR: Solutions to the challenges of dendrite control in Li metal anodes can provide safe next-generation rechargeable lithium metal batteries that have a long cycling life and can offer promise for other metal batteries.
Journal ArticleDOI
Conductive carbon nanofiber interpenetrated graphene architecture for ultra-stable sodium ion battery.
TL;DR: The authors construct carbon nanofiber interpenetrated graphene architecture with in-situ grown MoS2 nanoflakes alongside the framework, enabling outstanding electrochemical performance in sodium-ion battery.
Journal ArticleDOI
Solid polymer electrolyte soft interface layer with 3D lithium anode for all-solid-state lithium batteries
TL;DR: Li et al. as mentioned in this paper demonstrated that solid polymer electrolyte (SPE) soft interface layer was deposited on garnet electrolyte surface to endow connected interface between the electrolyte and electrodes and thus settled the interface contact issue.
References
More filters
Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.