Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Advanced Lithium Metal-Carbon Nanotube Composite Anode for High-Performance Lithium-Oxygen Batteries.
Feng Guo,Tuo Kang,Zhenjie Liu,Bo Tong,Bo Tong,Limin Guo,Wang Yalong,Liu Chenghao,Xi Chen,Yanfei Zhao,Yanbin Shen,Yanbin Shen,Wei Lu,Wei Lu,Liwei Chen,Liwei Chen,Liwei Chen,Zhangquan Peng +17 more
TL;DR: A lithium metal-carbon nanotube (Li-CNT) composite is reported as an alternative to the long-term untamed lithium electrode to address the critical issues associated with the lithium anode in Li-O2 batteries.
Journal ArticleDOI
Constructing Effective Interfaces for Li1.5Al0.5Ge1.5(PO4)3 Pellets To Achieve Room-Temperature Hybrid Solid-State Lithium Metal Batteries.
TL;DR: An effective solution to overcome the abovementioned problems is reported by introducing a three-dimensional gel polymer electrolyte at the interface between LAGP pellets and lithium metal anodes, achieving stable cycling of LiFePO4//Li cells at room temperature for 300 cycles.
Journal ArticleDOI
In-situ growth of hierarchical N-doped CNTs/Ni Foam scaffold for dendrite-free lithium metal anode
TL;DR: In this paper, a stable hierarchical scaffold is rationally designed for dendrite-free lithium metal anode (LMA) consisting of in-situ grown N-doped carbon nanotubes on the porous Ni foam (NCNT/NF), in which the interconnected NCNTs form the secondary structure and render numerous nucleation sites for uniform Li deposition.
Journal ArticleDOI
Facile interfacial adhesion enabled LATP-based solid-state lithium metal battery
Zelin Yang,Hongyan Yuan,Chuanjian Zhou,Yongmin Wu,Weiping Tang,Shangbin Sang,Hongtao Liu,Hongtao Liu +7 more
TL;DR: In this article, a facile interfacial adhesion strategy is proposed to solve the addressed issues, where the sticky polyethylene oxide (PEO) thin layer is served as interfacial adhesive to link the compact LATP ceramic electrolyte and the solid electrodes in consideration of its acceptable Li+ conducting capability and perfect compatibility with the tailored materials.
Journal ArticleDOI
Mechanochemical Synthesis of γ‐Graphyne with Enhanced Lithium Storage Performance
TL;DR: This work provides an environmentally benign and cost-effective mechanochemical method to synthesize γ-graphyne and demonstrates its superior Li+ storage experimentally.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.