Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Journal ArticleDOI
Atomic/molecular layer deposition for energy storage and conversion.
Yang Zhao,Lei Zhang,Jian Liu,Keegan R. Adair,Feipeng Zhao,Yipeng Sun,Tianpin Wu,Xuanxuan Bi,Khalil Amine,Jun Lu,Xueliang Sun +10 more
TL;DR: A comprehensive review of the development and achievements of ALD and MLD and their applications for energy storage and conversion, including batteries, supercapacitors, fuel cells, solar cells, and photoelectrochemical water splitting, is given in this paper.
Journal ArticleDOI
Impact of External Pressure and Electrolyte Transport Properties on Lithium Dendrite Growth
Journal ArticleDOI
Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes
TL;DR: The mechanism for the performance enhancement of lithium metal electrodes by fluoroethylene carbonate (FEC) is revealed in this paper, which shows that the solid electrolyte interphase (SEI) generated from FEC containing electrolytes is similar to the SEI generated from the baseline electrolyte, yet the corresponding Coulombic efficiencies are markedly different.
Journal ArticleDOI
Constructing a High-Strength Solid Electrolyte Layer by In Vivo Alloying with Aluminum for an Ultrahigh-Rate Lithium Metal Anode
Ziyang Lu,Ziyang Lu,Wantang Li,Wantang Li,Yu Long,Yu Long,Jiachen Liang,Jiachen Liang,Qinghua Liang,Shichao Wu,Shichao Wu,Ying Tao,Ying Tao,Zhe Weng,Zhe Weng,Wei Lv,Quan-Hong Yang,Quan-Hong Yang +17 more
TL;DR: In this paper, the construction of an Al-Li alloy/LiCl-based Li anode (ALA/Li anode) is reported by displacement and alloying reaction between an AlCl3−ionic liquid and a Li foil.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.