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Journal ArticleDOI

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

Changgu Lee, +4 more
- 18 Jul 2008 - 
- Vol. 321, Iss: 5887, pp 385-388
TLDR
Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
Abstract
We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.

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Journal ArticleDOI

Electronic-Mechanical Coupling in Graphene from in situ Nanoindentation Experiments and Multiscale Atomistic Simulations

TL;DR: In situ nanoindentation experiments performed on suspended graphene devices to introduce homogeneous tensile strain are presented, finding that the electrical resistance shows only a marginal change even under severe strain, and the electronic transport measurement confirms that there is no band gap opening for graphene under moderate uniform strain.
Journal ArticleDOI

Development of an Amperometric Cholesterol Biosensor Based on Graphene-Pt Nanoparticle Hybrid Material

TL;DR: In this paper, the authors developed a highly sensitive amperometric biosensor based on the hybrid material derived from nanoscale Pt particles (nPt) and graphene for the sensing of H2O2 and cholesterol.
Journal ArticleDOI

Preparation and swelling properties of graphene oxide/poly(acrylic acid-co-acrylamide) super-absorbent hydrogel nanocomposites

TL;DR: A series of novel graphene oxide (GO)/poly(acrylic acid-co-acrylamide) super-absorbent hydrogel nanocomposites were prepared by in situ radical solution polymerization as discussed by the authors.
Journal ArticleDOI

Nanodroplet activated and guided folding of graphene nanostructures.

TL;DR: In this article, water nanodroplets can be used as catalytic elements that initiate conformational changes and help to overcome deformation barriers associated with them, which can induce rapid bending, folding, sliding, rolling, and zipping of planar graphene nanostructures.
Journal ArticleDOI

Combination of photoelectrocatalysis and adsorption for removal of bisphenol A over TiO2-graphene hydrogel with 3D network structure

TL;DR: In this article, a 3D hydrogel of titanium dioxide (TiO2)-graphene was fabricated using a simple one-pot method and exhibited enriched adsorption-photoelectrocatalytic degradation ability of low-concentration bisphenol A (BPA).
References
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Journal ArticleDOI

Raman spectrum of graphene and graphene layers.

TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
Journal ArticleDOI

Two-dimensional atomic crystals

TL;DR: By using micromechanical cleavage, a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides are prepared and studied.
Journal ArticleDOI

The Phenomena of Rupture and Flow in Solids

TL;DR: In this article, the authors investigated the effect of surface scratches on the mechanical strength of solids, and some general conclusions were reached which appear to have a direct bearing on the problem of rupture, from an engineering standpoint, and also on the larger question of the nature of intermolecular cohesion.
Book

Physical properties of crystals

John F. Nye
TL;DR: In this paper, the physical properties of crystals systematically in tensor notation are presented, presenting tensor properties in terms of their common mathematical basis and the thermodynamic relations between them.
Journal ArticleDOI

Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load

TL;DR: The tensile strengths of individual multiwalled carbon nanotubes (MWCNTs) were measured with a "nanostressing stage" located within a scanning electron microscope and a variety of structures were revealed, such as a nanotube ribbon, a wave pattern, and partial radial collapse.
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