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Journal ArticleDOI

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

Changgu Lee, +4 more
- 18 Jul 2008 - 
- Vol. 321, Iss: 5887, pp 385-388
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TLDR
Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
Abstract
We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.

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The surface science of graphene: Metal interfaces, CVD synthesis, nanoribbons, chemical modifications, and defects

TL;DR: Graphene, a single atomic layer of sp2 hybridized carbon, exhibits a zero-band gap with linear band dispersion at the Fermi-level, forming a Dirac-cone at the K -points of its Brillouin zone as mentioned in this paper.
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Highly Compression‐Tolerant Supercapacitor Based on Polypyrrole‐mediated Graphene Foam Electrodes

TL;DR: A highly compressible supercapacitor has been fabricated by using newly developed polypyrrole-mediated graphene foam as electrode and achieves superb compression tolerance without significant variation of capacitances under long-term compressive loading and unloading processes.
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Graphene: An Emerging Electronic Material

TL;DR: The versatility of graphene-based devices goes beyond conventional transistor circuits and includes flexible and transparent electronics, optoelectronics, sensors, electromechanical systems, and energy technologies.
Journal ArticleDOI

Advances and challenges for flexible energy storage and conversion devices and systems

TL;DR: In this article, an overview of the remarkable contributions made by the leading scientists in this important and promising research area is given, and some perspectives for the future and impacts of flexible energy storage and conversion systems are also proposed.
Journal ArticleDOI

Solution Phase Production of Graphene with Controlled Thickness via Density Differentiation

TL;DR: Graphene flakes with controlled thicknesses are isolated in solution using density gradient ultracentrifugation, which results in graphene-surfactant complexes having buoyant densities that vary with graphene thickness.
References
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Journal ArticleDOI

Raman spectrum of graphene and graphene layers.

TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
Journal ArticleDOI

Two-dimensional atomic crystals

TL;DR: By using micromechanical cleavage, a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides are prepared and studied.
Journal ArticleDOI

The Phenomena of Rupture and Flow in Solids

TL;DR: In this article, the authors investigated the effect of surface scratches on the mechanical strength of solids, and some general conclusions were reached which appear to have a direct bearing on the problem of rupture, from an engineering standpoint, and also on the larger question of the nature of intermolecular cohesion.
Book

Physical properties of crystals

John F. Nye
TL;DR: In this paper, the physical properties of crystals systematically in tensor notation are presented, presenting tensor properties in terms of their common mathematical basis and the thermodynamic relations between them.
Journal ArticleDOI

Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load

TL;DR: The tensile strengths of individual multiwalled carbon nanotubes (MWCNTs) were measured with a "nanostressing stage" located within a scanning electron microscope and a variety of structures were revealed, such as a nanotube ribbon, a wave pattern, and partial radial collapse.
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