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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Improved solar cell performance of chemosynthesized cadmium selenide pebbles

TL;DR: In this paper, a simple and cost-effective one-step, one-pot chemical bath deposition method was used to synthesize the cadmium selenide pebble-like microstructures.
Journal ArticleDOI

Sb2S3-Sensitized Photoelectrochemical Cells: Open Circuit Voltage Enhancement through the Introduction of Poly-3-hexylthiophene Interlayer

TL;DR: In this paper, the Sb2S3-sensitized photoelectrochemical cells (Sb 2S3 -SPECs) in cobalt electrolyte were fabricated by depositing Sb 2 S 3 on the macroporous TiO2 nanorods electrodes and consecutively spin-coating P3HT interlayer to relieve the mass transport problem at vicinity of Sb S 3 and cobalt redox couples and reduce the backward recombination.
Journal ArticleDOI

CdS/TiO2-SrTiO3 heterostructure nanotube arrays for improved solar energy conversion efficiency

TL;DR: In this paper, the suppression of charge recombination at electrode surface is shown to be critical to efficient solar energy conversion, and the performance of CdS/TiO2/SrTiO3 electrode exhibits a superior photo-electrochemical performance than CcTiO 2 electrode with ∼ 70% increase in external quantum efficiency.
Journal ArticleDOI

Energy transfer versus charge separation in hybrid systems of semiconductor quantum dots and Ru-dyes as potential co-sensitizers of TiO2-based solar cells

TL;DR: In this paper, the type II energy level alignment between colloidal quantum dots and both N3 and Ru505 offers a possibility for the directional charge separation, with electrons transferred to the QDs and holes to the dye.
Journal ArticleDOI

Tuning the light absorption of Cu 1.97 S nanocrystals in supercrystal structures

TL;DR: In this paper, the light absorption properties of Cu1.97S nanocrystals were tuned toward the red part of the visible spectrum by adding ligands to the supercrystals.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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