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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

A stable inverse opal structure of cadmium chalcogenide for efficient water splitting

TL;DR: In this paper, the inverse opal structure (IOS) composed of Cadmium chalcogenide nanocrystals (CCNCs) was designed to achieve an unprecedentedly high photocurrent and hydrogen production rate.
Journal ArticleDOI

P-type CoO nanowire arrays and their application in quantum dot-sensitized solar cells

TL;DR: In this paper, the p-type cobalt oxide (CoO) nanowire arrays were synthesized via a hydrothermal process followed by thermal annealing, and n-type CdS/CoO nano-heterojunctions were utilized as the photocathode of solar cells.
Journal ArticleDOI

Interfacial engineering of quantum dot-sensitized TiO2 fibrous electrodes for futuristic photoanodes in photovoltaic applications

TL;DR: In this article, a generic surface treatment approach was proposed to improve the electronic interfaces of quantum dot-sensitized TiO2 fiber electrodes, thereby promoting their photo-anode performance.
Journal ArticleDOI

A facile strategy for the preparation of ZnS nanoparticles deposited on montmorillonite and their higher catalytic activity for rapidly colorimetric detection of H2O2.

TL;DR: The as-prepared ZnS-MMT nanocomposites have been proven to possess intrinsic peroxidase-like activity that can rapidly catalyze the reaction of per oxidase substrate 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2 and produce a blue color product in less than 30 seconds, which provides a sensitive colorimetric sensor to detect H 2O2.
Journal ArticleDOI

The Effects of Particle Concentration and Surface Charge on the Oriented Attachment Growth Kinetics of CdTe Nanocrystals in H2O

TL;DR: In this paper, the growth kinetics of thioglycolic acid (TGA)-capped CdTe nanoparticles in H2O were studied at different particle concentrations, with the aim to understand the effects of concentration and surface state of primary particles on the growth mechanism of nanocrystals.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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