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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Topotactically Grown Bismuth Sulfide Network Film on Substrate as Low-Cost Counter Electrodes for Quantum Dot-Sensitized Solar Cells

TL;DR: In this article, a two-dimensional interconnected Bi2S3 single-crystalline nanorod networks have been fabricated on a F:SnO2 (FTO) glass substrate through the formation of intermediate BiOI nanosheets from layer-structured BiI3 by chemical vapor deposition and subsequent hydrothermal transformation into Bi 2S3 networks.
Journal ArticleDOI

Improve photo-electron conversion efficiency of ZnO/CdS coaxial nanorods by p-type CdTe coating

TL;DR: Electrochemical impedance spectroscopy characterization suggests that the stepwise band structure of ZnO/CdS/C dTe is conducive to improving charge separation and extending the electron diffusion length, finally contributing to a high conversion efficiency.
Journal ArticleDOI

Computational simulation of the p‐n doped silicon quantum dot

TL;DR: In this article, a longated crystalline silicon quantum dot (QD) codoped with aluminum and phosphorous together has been modeled with a formula of Si36Al1P1H42.
Journal ArticleDOI

Spectral optimization of color temperature tunable white LEDs based on perovskite quantum dots for ultrahigh color rendition

TL;DR: In this article, the spectral optimization for maximizing limited luminous efficacy (LLE) of tunable white light-emitting diodes (LEDs) with two, three and four color perovskite quantum dots (QDs) excited by a blue chip was investigated under the constraint of designated ultrahigh color rendering index (CRI) and color quality scale (CQS).
Journal ArticleDOI

Electrospun TiO2 nanostructures sensitized by CdS in conjunction with CoS counter electrodes: Quantum dot-sensitized solar cells all prepared by successive ionic layer adsorption and reaction

TL;DR: In this article, a CdS QDSC featuring CoS counter electrode that is all prepared by successive ionic layer adsorption and reaction (SILAR) method is reported.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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