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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Graphene and its derivatives for the development of solar cells, photoelectrochemical, and photocatalytic applications

TL;DR: Gatys et al. as mentioned in this paper summarized the state of research on graphene-based materials from the standpoint of photoelectrochemistry and discussed the prospects and further developments in this exciting field of research.
Journal ArticleDOI

Photoanodes Based on TiO$_2$ and $\alpha$-Fe$_2$O$_3$ for Solar Water Splitting Superior Role of 1D Nanoarchitectures and of Combined Heterostructures

TL;DR: In this paper, a review describes various synthetic methods, properties and PEC applications of 1D-photoanodes (nanotubes, nanorods, nanofibers, nanowires) based on titania, hematite, and on $\alpha$-Fe$_2$O$_3$/TiO$-2$ heterostructures.
Journal ArticleDOI

Hot Exciton Relaxation Dynamics in Semiconductor Quantum Dots: Radiationless Transitions on the Nanoscale

TL;DR: In this paper, the femtosecond state-resolved pump/probe experiments on colloidal CdSe quantum dots were conducted to provide the first quantitative measure of excitonic state-to-state transition rates.
Journal ArticleDOI

Potential applications of hierarchical branching nanowires in solar energy conversion

TL;DR: In this paper, the authors suggest that more complex nanostructures, both in the form of hierarchically branching/hyperbranching nanowire structures and in the case of multi-component nanowires of diverse materials, are potentially even more interesting for solar energy harvesting and conversion.
Journal ArticleDOI

Colloidal Quantum Dot Photovoltaics: A Path Forward

TL;DR: A prescription is closed with a prescription, expressed as bounds on the density and energy of electronic states within the CQD film band gap, that should allow device efficiencies to rise to those required for the future of the solar energy field.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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