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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Quantum dot-sensitized solar cells—perspective and recent developments: A review of Cd chalcogenide quantum dots as sensitizers

TL;DR: In this article, the concept and mechanism behind quantum dot-sensitized solar cells (QDSSCs) are reviewed, and possible approaches for improving the Cd chalcogenide QDSSC performance are also discussed.
Journal ArticleDOI

Solution-phase synthesis of SnSe nanocrystals for use in solar cells.

TL;DR: Preliminary solar cell devices incorporating SnSe nanocrystals into a poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylenevinylene] matrix demonstrate a significant enhancement in quantum efficiency and short-circuit current density, suggesting that this earth-abundant material could be a valuable component in future photovoltaic devices.
Journal ArticleDOI

Energy Transfer from Quantum Dots to Metal–Organic Frameworks for Enhanced Light Harvesting

TL;DR: The functionalization of porphyrin-basedMOFs with CdSe/ZnS core/shell quantum dots (QDs) for the enhancement of light harvesting via energy transfer from the QDs to the MOFs with efficiencies of more than 80% is reported.
Journal ArticleDOI

Cu2Se Nanoparticles with Tunable Electronic Properties Due to a Controlled Solid-State Phase Transition Driven by Copper Oxidation and Cationic Conduction

TL;DR: Stoichiometric copper(I) selenide nanoparticles have been synthesized using the hot injection method and enhanced electronic properties can be explained by the oxidation of Cu(+) and Se(2-) on the nanoparticle surface, ultimately leading to a solid-state conversion of the core from monoclinic Cu(2)Se to cubic Cu(1.8)Se.
Journal ArticleDOI

(Photo)electrochemical Methods for the Determination of the Band Edge Positions of TiO2-Based Nanomaterials

TL;DR: In this article, a detailed discussion of several electrochemical, photoelectrochemical, and spectroelectronic methods that can be applied for the determination of band edge positions in compact and nanocrystalline thin films, as well as in nanocrystine powders.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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