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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
Journal ArticleDOI

Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

TL;DR: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each that are among the hottest research topics of the last decades.
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Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells

TL;DR: In this paper, the authors discussed the steps that have led to this discovery, and the future of this rapidly advancing concept have been considered, and it is likely that the next few years of solar research will advance this technology to the very highest efficiencies while retaining the very lowest cost and embodied energy.
References
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Journal ArticleDOI

Highly Efficient Multiple Exciton Generation in Colloidal PbSe and PbS Quantum Dots

TL;DR: It is found that the biexciton effect, which shifts the transition energy for absorption of a second photon, influences the early time transient absorption data and may contribute to a modulation observed when probing near the lowest interband transition.
Journal ArticleDOI

Controlling anisotropic nanoparticle growth through plasmon excitation

TL;DR: It is demonstrated that the previously described photoinduced method for converting silver nanospheres into triangular silver nanocrystals—so-called nanoprisms—can be extended to synthesize relatively monodisperse nanoprism with desired edge lengths in the 30–120 nm range.
Journal ArticleDOI

Analysis of optical absorption in silicon nanowire arrays for photovoltaic applications.

TL;DR: Analysis of the optical absorption in silicon nanowires arrays that have potential applications in solar cells reveals that nanowire arrays with moderate filling ratio have much lower reflectance compared to thin films.
Journal ArticleDOI

Quantum-Sized PbS, CdS, Ag2S, Sb2S3, and Bi2S3 Particles as Sensitizers for Various Nanoporous Wide-Bandgap Semiconductors

TL;DR: In this article, the photocurrent quantum yield reached values of more than 70% for Q-CdS and Q-PbS sensitized electrodes, while the amount of light absorption is negligibly small.
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