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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Efficient Semiconductor-Sensitized Solar Cells Based on Poly(3-hexylthiophene)@CdSe@ZnO Core−Shell Nanorod Arrays

TL;DR: In this paper, an efficient semiconductor-sensitized solar cell (SSC) based on the poly(3-hexylthiophene) (P3HT)@CdSe@ZnO core−shell nanorod arrays as a photoanode was evaluated.
Journal ArticleDOI

Facile solution growth of vertically aligned ZnO nanorods sensitized with aqueous CdS and CdSe quantum dots for photovoltaic applications.

TL;DR: The in situ growth of ZnO nanorod arrays in a solution containing CdSe quantum dots provides better contact between two materials resulting in enhanced open circuit voltage.
Journal ArticleDOI

Synthesis, photophysical properties and surface chemistry of chalcopyrite-type semiconductor nanocrystals

TL;DR: In this paper, a review of the current understanding of the optical properties of chalcopyrite-type nanocrystals is presented, both in organic solvents and in the aqueous phase.
Journal ArticleDOI

Photoinduced Electron Transfer Between Pyridine Coated Cadmium Selenide Quantum Dots and Single Sheet Graphene

TL;DR: In this paper, photoinduced electron transfer between red-emitting CdSe quantum dots and the single-sheet graphene with areas of several square centimeters was investigated. But the results were limited to femtosecond and picosecond time-domains.
Journal ArticleDOI

Visible light activated room temperature gas sensors based on nanocrystalline ZnO sensitized with CdSe quantum dots

TL;DR: In this paper, the photoconductivity and visible light activated room temperature gas sensors properties of nanocrystalline ZnO thick films sensitized with colloidal CdSe quantum dots (QDs) were studied.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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