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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
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Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

TL;DR: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each that are among the hottest research topics of the last decades.
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Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells

TL;DR: In this paper, the authors discussed the steps that have led to this discovery, and the future of this rapidly advancing concept have been considered, and it is likely that the next few years of solar research will advance this technology to the very highest efficiencies while retaining the very lowest cost and embodied energy.
References
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Journal ArticleDOI

Time-resolved electrostatic force microscopy of polymer solar cells.

TL;DR: Time-resolved electrostatic force microscopy is introduced as a means to measure photoexcited charge in polymer films with a resolution of 100’nm and 100 μs, and data show that the domain centres account for the majority of the photoinduced charge collected in polyfluorene blend devices.
Journal ArticleDOI

Efficient Generation of Photocurrents by Using CdS/Carbon Nanotube Assemblies on Electrodes

TL;DR: This work has shown that the transfer of conduction-band electrons to the electrode (or the supply of electrons from the electrode to the valence-band holes)—the processes that lead to the photocurrents—are hampered by the competing electron–hole recombination process, which degrades the process.
Journal ArticleDOI

Attachment of Single CdSe Nanocrystals to Individual Single-Walled Carbon Nanotubes

TL;DR: In this paper, single amine functionalized CdSe quantum dots were coupled to individual acid-chloride modified single-walled carbon nanotubes via amide bond formation.
Journal ArticleDOI

Photoluminescence from Single Semiconductor Nanostructures

TL;DR: In this article, a review of recent results in the spectroscopy of single CdSe nanocrystal quantum dots is presented, including ultra-narrow emission lineshapes (∼600× narrower than ensemble spectra), a highly polarizable emitting state in the presence of strong local electric fields, line broadening as a result of environmental fluctuations, and shifting of the emission spectra over a wide range of energies.
Journal ArticleDOI

Electron Transfer Dynamics in Nanocrystalline Titanium Dioxide Solar Cells Sensitized with Ruthenium or Osmium Polypyridyl Complexes

TL;DR: In this article, the electron transfer dynamics in solar cells that utilize sensitized nanocrystalline titanium dioxide photoelectrodes and the iodide/triiodide redox couple have been studied on a nanosecond time scale.
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