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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
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Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

TL;DR: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each that are among the hottest research topics of the last decades.
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Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells

TL;DR: In this paper, the authors discussed the steps that have led to this discovery, and the future of this rapidly advancing concept have been considered, and it is likely that the next few years of solar research will advance this technology to the very highest efficiencies while retaining the very lowest cost and embodied energy.
References
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Journal ArticleDOI

An overview of solution-based semiconductor nanowires: synthesis and optical studies

TL;DR: This Perspective describes recent progress in the synthesis and optical characterization of high quality solution-based semiconductor nanowires (NWs) and proposes a "geminate" NW nucleation mechanism that is predictive of intrawire optical heterogeneity and fluorescence intermittency at the single NW level.
Journal ArticleDOI

Dynamic Burstein-Moss shift in semiconductor colloids

TL;DR: In this paper, photoinduced blue shifts in CdS colloids have been time resolved by picosecond pump-probe measurements, and the predicted shifts are greater than observed values at the higher light intensities.
Journal ArticleDOI

C60 Cluster as an Electron Shuttle in a Ru(II)-Polypyridyl Sensitizer-Based Photochemical Solar Cell

TL;DR: In this article, a redox-active molecular assembly was employed as an electron relay that greatly minimizes the interaction with the excited dye while maintaining the effectiveness of the regeneration cycle.
Journal ArticleDOI

Photoelectrochemistry of Composite Semiconductor Thin Films. Photosensitization of SnO2/CdS Coupled Nanocrystallites with a Ruthenium Polypyridyl Complex

TL;DR: In this article, the authors investigated the effect of charge injection from an excited Ru(II) complex (viz., (Ru(bpy)2(L))2+, where L = 4-(2,2‘-bipyrid-4-yl)phenyl diphosphonate) into SnO2 and SnO 2/CdS films to elucidate the beneficial effect of composite semiconductor systems.
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