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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
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TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Far- and deep-ultraviolet spectroscopic investigations for titanium dioxide: electronic absorption, Rayleigh scattering, and Raman spectroscopy

TL;DR: In this paper, the historic and recent research studies of TiO2 in these areas are overviewed, and recent marked progress on attenuated total reflectance (ATR) DUV-FUV spectroscopy, resonant DUV Rayleigh scattering spectrograms, and DUV Raman spectrographs are focused on intensively.
Journal ArticleDOI

Effect of metal oxide morphology on electron injection from CdSe quantum dots to ZnO

TL;DR: In this paper, the acceptor morphology has a significant impact on electron injection due to change in material permittivity and different density of the band-edge states, and the results open a reference to improve injection efficiency in quantum dot-metal oxide system by selection of the acceptors morphology.
Journal ArticleDOI

Hot Charge Carrier Extraction from Semiconductor Quantum Dots

TL;DR: In this paper, the authors focus on the recent work carried out on hot charge carrier extraction from colloidal quantum dots (QDs), and it has been contemplated that the quantum dot based solar cell (QDSC) can reach...
Journal ArticleDOI

CdS quantum dots sensitized TiO2 nanorod-array-film photoelectrode on FTO substrate by electrochemical atomic layer epitaxy method

TL;DR: In this paper, high quality CdS/TiO 2 /FTO nanorod-array film photoelectrodes were fabricated by electrochemical atomic layer epitaxy method (ECALE).
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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