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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Journal ArticleDOI

Ex Situ CdSe Quantum Dot-Sensitized Solar Cells Employing Inorganic Ligand Exchange To Boost Efficiency

TL;DR: In this paper, an effective way to boost the as-synthesized CdSe quantum dot-sensitized solar cells performance by introducing an inorganic ligand exchange strategy into this traditional system is presented.
Journal ArticleDOI

Hybrid CdSe/TiO2 nanowire photoelectrodes: Fabrication and photoelectric performance

TL;DR: In this article, annealing treatments at various temperatures (350 °C, O2, N2, Ar, and vacuum) are used to improve the performance of the as-deposited photoelectrode and the effects of various annesaling atmospheres (air, O 2, N 2, Ar and vacuum).
Journal ArticleDOI

Graphene frameworks promoted electron transport in quantum dot-sensitized solar cells.

TL;DR: Results revealed that the GFs/TiO2 electrode has a shorter electron transport time, as well as longer electron lifetime and diffusion path length, than conventional 2D graphene sheets/Ti O2 electrode, thus indicating that GFs could promote rapid electron transfer in TiO2 photoanodes.
Journal ArticleDOI

In-situ synthesis of CdS/g-C3N4 hybrid nanocomposites with enhanced visible photocatalytic activity

TL;DR: In this article, a simple in situ synthetic strategy was used to fabricate CdS/g-C3N4 hybrid nanocomposite catalysts with visible-light-driven photocatalytic activity from cadmium-containing carbon nitride compounds.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
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