scispace - formally typeset
Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

read more

Citations
More filters
Journal ArticleDOI

Spectroscopic insights into high defect tolerance of Zn:CuInSe2 quantum-dot-sensitized solar cells

TL;DR: In this article, surface modifications have surprisingly little effect on photovoltaic performance suggesting that intragap defects do not impede but actually assist the photoconversion process in Zn:CuInSe2 QDs.
Journal ArticleDOI

Copper–indium–selenide quantum dot-sensitized solar cells

TL;DR: A new synthetic process of near infrared (NIR)-absorbing copper-indium-selenide (CISe) quantum dots (QDs) and their applications to efficient and completely heavy-metal-free QD-sensitized solar cells (QDSCs).
Journal ArticleDOI

Inverted Colloidal Quantum Dot Solar Cells

TL;DR: An inverted architecture of quantum dot solar cells is demonstrated by introducing a novel ZnO method on top of the PbS CQD film, which improves device characteristics and provides a further electronic advantage.
Journal ArticleDOI

Copper deficient Zn–Cu–In–Se quantum dot sensitized solar cells for high efficiency

TL;DR: In this paper, high quality composition controllable Zn-Cu-In-Se (ZCISe) QDs were synthesized, and the influence of non-stoichiometry on the optoelectronic properties, as well as on the photovoltaic performance of the resulting QDSCs, was investigated systematically.
Journal ArticleDOI

Exceptional catalytic efficiency in mineralization of the reactive textile azo dye (RB5) by a combination of ultrasound and core-shell nanoparticles (CdS/TiO2).

TL;DR: The selected combined method (sonocatalysis) was able to decolorize and oxidize simultaneously the organic dye with a complete mineralization into SO(4)(2-) and NO(3)(-) ions.
References
More filters
Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

Carbon Nanotubes--the Route Toward Applications

TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment

TL;DR: In this paper, the authors describe recent progress in the theory of nanoparticle optical properties, particularly methods for solving Maxwell's equations for light scattering from particles of arbitrary shape in a complex environment.
Journal ArticleDOI

Semiconductor Nanocrystals as Fluorescent Biological Labels

TL;DR: Semiconductor nanocrystals prepared for use as fluorescent probes in biological staining and diagnostics have a narrow, tunable, symmetric emission spectrum and are photochemically stable.
Related Papers (5)