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Journal ArticleDOI

Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters

Prashant V. Kamat
- 18 Oct 2008 - 
- Vol. 112, Iss: 48, pp 18737-18753
TLDR
In this paper, three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell, (ii) polymer−smiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell.
Abstract
The emergence of semiconductor nanocrystals as the building blocks of nanotechnology has opened up new ways to utilize them in next generation solar cells. This paper focuses on the recent developments in the utilization of semiconductor quantum dots for light energy conversion. Three major ways to utilize semiconductor dots in solar cell include (i) metal−semiconductor or Schottky junction photovoltaic cell (ii) polymer−semiconductor hybrid solar cell, and (iii) quantum dot sensitized solar cell. Modulation of band energies through size control offers new ways to control photoresponse and photoconversion efficiency of the solar cell. Various strategies to maximize photoinduced charge separation and electron transfer processes for improving the overall efficiency of light energy conversion are discussed. Capture and transport of charge carriers within the semiconductor nanocrystal network to achieve efficient charge separation at the electrode surface remains a major challenge. Directing the future resear...

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Citations
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Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
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Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

TL;DR: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each that are among the hottest research topics of the last decades.
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Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells

TL;DR: In this paper, the authors discussed the steps that have led to this discovery, and the future of this rapidly advancing concept have been considered, and it is likely that the next few years of solar research will advance this technology to the very highest efficiencies while retaining the very lowest cost and embodied energy.
References
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Journal ArticleDOI

Mechanisms for intraband energy relaxation in semiconductor quantum dots: The role of electron-hole interactions

TL;DR: In this article, the role of electron-hole (e-h) interactions in quantum dots has been investigated and it has been shown that electron relaxation is dominated not by phonon emission but by the e-h energy transfer.
Journal ArticleDOI

Wave function engineering in elongated semiconductor nanocrystals with heterogeneous carrier confinement

TL;DR: Two routes to wave function engineering in elongated colloidal CdSe/CdS quantum dots are explored, providing deep insight into the intrinsic physics of these low-dimensional heterostructures, opening applications as electrically switchable single photon sources.
Journal ArticleDOI

Polythiophene containing thermally removable solubilizing groups enhances the interface and the performance of polymer-titania hybrid solar cells.

TL;DR: A polythiophene derivative containing thermally removable branched ester solubilizing groups has been prepared and tested as a processable organic semiconductor polymer with tunable electronic and chemical properties for hybrid polymer-inorganic solar cells.
Journal ArticleDOI

Structural and spectroscopic investigations of CdS/HgS/CdS quantum-dot quantum wells.

TL;DR: Epitaxial growth in a CdS/HgS heterostructure of nanometer dimensions, prepared by methods of wet chemistry, is demonstrated and photophysical measurements provide evidence for charge-carrier localization within the HgS well.
Journal ArticleDOI

Molecular approaches to solar energy conversion with coordination compounds anchored to semiconductor surfaces.

TL;DR: Tuning the energetic position of the semiconductor conduction band relative to the molecular sensitizer has provided new insights into interfacial charge transfer, and approaches for enhancing charge-separation lifetimes for solar energy conversion are presented.
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