Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Synthesis and structure of new Zn(II) and Co(II) coordination polymers with 1,3,5-benzenetricarboxylic acid
TL;DR: In this paper, the tetrahedral Zn(II) coordination polyhedron is formed by the N2O2 set of donor atoms: the O atoms belong to two different carboxylate ligands, HBtc2- and (Me)Btc2−, while the N atoms belonging to two Bpp ligands.
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Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4'-bipyridine)2(NCS)2]n.
TL;DR: In this paper , the variable switching behavior of a previously known square lattice topology, [Ni(4,4'-bipyridine)2(NCS)2] (sql-1-Ni-NCS), with respect to nine gaseous adsorbates was investigated.
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Room temperature synthesis of a luminescent crystalline Cu–BTC coordination polymer and metal–organic framework
TL;DR: Synthesis of crystalline materials is elemental in the field of coordination chemistry towards optical applications as discussed by the authors , and crystalline material synthesis is an important area of research in coordination chemistry.
Journal ArticleDOI
Synthesis, characterization, and crystal structure of catena-poly[bis(carboxybenzenesulfonato)-bis(1,10-phenanthroline)lead(II)0.5(4,4′-bipy)]
TL;DR: In this paper, a new lead complex was synthesized and characterized by single-crystal X-ray, infrared, and thermogravimetric analyses and fluorescence studies, where the lead atom is hexacoordinated by two N atoms of one phen ligand and four O atoms from three 4-sb dianions.
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Response surface optimisation of an oxalate–phosphate–amine metal–organic framework (OPA-MOF) of iron and urea
TL;DR: In this article, the synthesis and synthesis-optimisation of a novel oxalate-phosphate-amine MOF (OPA-MOF) for innovative agricultural applications is described, with urea as a structure-directing agent in a hydrothermal synthesis.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.