Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Reversible recrystallization process of copper and silver thioacetamide-halide coordination polymers and their basic building blocks†
TL;DR: In this article, the processability of coordination polymers on glass for the production of organized thin films has been investigated and preliminary results of 2 on glass have been shown for 3 and 4 in pyridine.
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Benchmarking of GGA density functionals for modeling structures of nanoporous, rigid and flexible MOFs
TL;DR: It is shown that the dispersion long range correction is essential to stabilize the structures and, in some cases, to converge the system to a geometry that is in line with the experimentally observed structure, especially for breathing MIL-53 structures or zeolitic imidazolate frameworks.
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Mixed-ligand cobalt, nickel and zinc coordination polymers based on flexible 1,4-bis((1H-imidazol-1-yl)methyl)benzene and rigid carboxylate linkers
TL;DR: The mixed-ligand coordination polymers {[Zn(BIX) 2.5 ](NO 3 ) 2 ·5.5H 2 O} n (1), {[Co(BiX) 3 ](No 3 )2 ·4 H 2 O] n (2), [Ni(BIx) 2 (BDC) 2(BDC), [Zn 2 (BIX)(BTC)(OH)]·H 2O} n(3 ) and {Zn 0.5 (HIDC)] n (4), [
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Robust MOFs of "tsg" Topology Based on Trigonal Prismatic Organic and Metal Cluster SBUs: Single Crystal to Single Crystal Postsynthetic Metal Exchange and Selective CO2 Capture.
TL;DR: The high symmetry and structural attributes of the organic linker seemingly dictate adoption of the trigonal-prismatic metal cluster SBU by the metal ions in the MOFs, and the isostructural robust MOFs exhibit significant gas sorption and remarkable selectivity for CO2 over N2 at ambient conditions.
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Comparing gas separation performance between all known zeolites and their zeolitic imidazolate framework counterparts.
TL;DR: This work is pioneering at examining the families comprised by the experimentally known zeolites and their respective Zeolitic Imidazolate Framework (ZIF) counterparts in the context of a number of environmental and industrial separations involving carbon dioxide, nitrogen, methane, oxygen, and argon.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.