Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Journal ArticleDOI
Synthesized and Characterization of a new Cd(II)-based coordination polymer: sensing activity and photocatalytic activity against antibiotic
Yan Du,Mithun Kumar Ghosh,Lu Lu,Jun Wang,Aurobinda Mohanty,Tanmay Kumar Ghorai,Mohd Afzal,Abdullah Alarifi +7 more
TL;DR: In this paper , a new coordination polymer with formula [Cd4(2.2'-bipy)4(HL)2·H2O] has been synthesized by single X-ray diffraction, FT-IR, UV-visible spectroscopy and TGA.
Book ChapterDOI
MOF and its application in electrochemistry
TL;DR: In this article , metal-organic frameworks (MOFs) are discussed in potential reactions like oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and hydrogen evolution reaction(HER).
Journal ArticleDOI
Green halogenation of aromatic compounds using environmentally friendly synthesized rod-like metal-organic framework (MIL-88A) catalyst
TL;DR: The rod-like MIL-88A was used as an efficient catalyst for the halogenation of aromatic materials (aniline, b-naphthol, and naphthalene) as discussed by the authors .
Synthesis, Structure and Magnetic Properties of a 3D Interpentrating Network Based on 4-Imidazol-1-yl-benzoic Acid and Azide Ligands
TL;DR: A new CoII coordination complex was prepared by the hydrothermal reaction of Co(NO3)2·6H2O with NaN3 in the presence of 4-imidazol-1-yl-benzoic acid (Hiba).
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.