Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
A rare metal–organic 3D architecture with a pseudo-primitive cubic topology with double edges constructed from a 12-connected SBU
Yi-Hang Wen,Yi-Hang Wen,Jian Zhang,Xiao-Qin Wang,Yun-Long Feng,Jian-Kai Cheng,Zhao-Ji Li,Yuan-Gen Yao +7 more
TL;DR: In this paper, a pseudo-primitive cubic (pcu) topology with double edges constructed from a 12-connected SBU was presented, where the double edges were constructed from the SBU itself.
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Syntheses and crystal structures of iron co-ordination polymers with 4,4′-bipyridine (4,4′-bpy) and 4,4′-azopyridine (azpy). Two-dimensional networks supported by hydrogen bonding, {[Fe(azpy)(NCS)2(MeOH)2]·azpy}n and {[Fe(4,4′-bpy)(NCS)2(H2O)2]·4,4′-bpy}n
TL;DR: In this article, two types of bridging ligands, directly bridging iron centers to form a one-dimensional chain of [Fe(L)] (L ǫ = 4,4′-bpy) and indirectly bridging pyridine nitrogen atoms and co-ordinated methanol or water molecules, are presented.
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Construction of co-ordination networks of 1,6-bis(4′-pyridyl)-2,5-diazahexane with silver(I) and copper(I). Structural diversity through change in metal ions and counter ions
TL;DR: In this paper, a flexible tetradentate ligand 1,6-bis(4′-pyridyl)-2,5-diazahexane (BPDH) was synthesized, and its coordination networks with silver (I) and copper(I) salts chracterized by X-ray single-crystal structure analysis and electrospray mass spectrometry (ES-MS).
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Study of the iron/trimesic acid system for the hydrothermal synthesis of hybrid materials
TL;DR: Two divalent iron trimesates were synthesized hydrothermally at 453 K for 72 hours under autogenous pressure using 1,3,5-benzenetricarboxylic acid (or trimesic acid, symbolized by BTC-H3).
Journal ArticleDOI
Energy and electron transfers in photosensitive chitosan.
TL;DR: The photosensitive chitosan developed herein could could act as an efficient photosensitizer and lead to the application of the environmentally friendly photocatalytic system for an efficient degradation of a wide range of pollutants.