Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Synthesis, Structures, and Water Adsorption of Two Coordination Polymers Constructed by M(II) (M = Ni (1) and Zn (2)) with 1,3-Bis(4-Pyridyl)Propane (bpp) and 1,2,4,5-Benzenetetracarboxylate (BT4-) Ligands.
Chih-Chieh Wang,Wei-Cheng Yi,Zi-Ling Huang,Tsai-Wen Chang,Wen-Chi Chien,Yueh-Yi Tseng,Bo-Hao Chen,Yu-Chun Chuang,Gene-Hsiang Lee +8 more
TL;DR: Two coordination polymers, with chemical formulas, have been synthesized and structurally characterized by single-crystal X-ray diffraction methods, and the reversible water de-/adsorption behavior of 1 between dehydrated and rehydrated forms has been verified by cyclic Thermogravimetric (TG) analyses.
Journal ArticleDOI
An antiferromagnetic metal-organic framework with high symmetry octanuclear Mn8(μ4-O)3(COO)12 secondary building units
TL;DR: In this paper, a new antiferromagnetic 3D metal-organic framework with octanuclear Mn8(μ4-O)3(COO)12 secondary building unit (SBU) has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and infrared spectroscopy.
Journal ArticleDOI
Structural and Thermal Investigations of Co(II) and Ni(II) Coordination Polymers Based on biphenyl-4,4'-dioxydiacetate Linker.
TL;DR: In this paper, two coordination polymers, [Co(µ4-L)(H2O)2]n (1) and [Ni( µ-L), H2O4]-n (2), were solvothermally assembled from the corresponding metal(II) chlorides and biphenyl-4, 4,4-dioxydiacetic acid (H2L) as a flexible dicarboxylate linker.
Journal ArticleDOI
One-step conversion of syngas to hydrocarbons and ethers over ZIF-8 derived ZnO coupling HZSM-5
TL;DR: In this paper, the performance of bifunctional catalysts in syngas conversion was investigated in a fixed-bed tubular reactor, and the results demonstrate that the pyrolysis temperature has an important influence on the particle size of ZnO.
Journal ArticleDOI
Switching of support materials for the hydrogenation of nitroarenes: A review
TL;DR: In this paper , a review of the recent progress in support materials tuning strategies to enhance catalytic performance for the hydrogenation of nitroarenes is presented, and the importance of support materials in the heterogeneous catalytic hydrogenation is discussed.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.