Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
Reads0
Chats0
TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
More filters
Journal ArticleDOI
Hydrophilic Microporous Lanthanide-Organic Frameworks Based on 4,4'-Biphenyldiacetate: Synthesis, Crystal Structures and Sorption Properties
TL;DR: In this article, 15 microporous coordination polymers of symmetrical and flexible 4,4′-biphenyldiacetate (bpda2)-with lanthanide(III) cations (Ln3+) of formula {[Ln2(bpda)3(H2O)]⋅2H 2O}n with an infinite secondary building unit (SBU) were synthesized and characterized.
Journal ArticleDOI
Current Trend in Synthesis, Post‐Synthetic Modifications and Biological Applications of Nanometal‐Organic Frameworks (NMOFs)
Journal ArticleDOI
Designing Magnetic NanoMOFs for Biomedicine: Current Trends and Applications
Mariangela Oggianu,Noemi Monni,Valentina Mameli,Carla Cannas,Suchithra Ashoka Sahadevan,Maria Laura Mercuri +5 more
TL;DR: An overview of current trends on the design of magnetic nanoMOFs in the field of biomedicine, with particular emphasis on theranostics and bioimaging, is herein envisioned.
Journal ArticleDOI
Sulfate removal by barium-terephthalate MOF synthesized from recycled PET-waste using Doehlert design optimization
TL;DR: In this paper , a barium-terephthalate metal-organic framework (Ba(BDC)) was synthesized as a new efficient adsorbent by an aqueous media method.
Journal ArticleDOI
A Novel Twofold Interpenetrating 2D (3,5)-Connected Cd(II) Coordination Framework with (5 2 .6)(5 5 .6 4 .7) Topology
TL;DR: In this paper, the Cd(II) atoms as 5-connected nodes are linked by the bridging ligands L acting as both linear connectors and 3-connections to form a novel (3, 5)-connected 2D framework with the (52.6)(55.64.7) topology.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.