Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
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Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Hydrogen storage in metal–organic frameworks
TL;DR: The role of porous metal-organic frameworks (MOFs) as storage materials for hydrogen (H2) and the current state-of-the-art in this rapidly developing field are reviewed in this article.
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Novel Photocatalysts for the Decomposition of Organic Dyes Based on Metal-Organic Framework Compounds
TL;DR: Three novel metal-organic frameworks with three-dimensional structures have been synthesized and characterized and indicate that they are active catalysts for the degradation of orange G, rhodamine B, Remazol Brilliant Blue R and methylene blue.
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Crystal Engineering of a Nanoscale Kagomé Lattice
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Recent Advances in Supramolecular Design and Assembly of Silver(i) Coordination Polymers
TL;DR: A short review of recent advances in the design and construction of Ag(i) coordination polymers with special emphasis on the Ag ion coordination geometry, ligand functionality, and supramolecular interactions is provided in this article.
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Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks
Franck Millange,Nathalie Guillou,Richard I. Walton,Jean-Marc Greneche,Irene Margiolaki,Gérard Férey +5 more
TL;DR: The thermal behaviour of the nanoporous iron(iii) terephthalate MIL-53 is in stark contrast to its chromium and aluminium analogues which show an expansion of the cell during dehydration; with iron, reversible dehydration occurs via evolution of the structure through a highly distorted metastable anhydrous phase to a more regular phase above 423 K.