Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Metal@MOF: Loading of Highly Porous Coordination Polymers Host Lattices by Metal Organic Chemical Vapor Deposition
Stephan Hermes,Marie-Katrin Schröter,Rochus Schmid,Lamma Khodeir,Martin Muhler,Arno Dr. Tissler,Richard W. Fischer,Roland A. Fischer +7 more
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Using molecular simulation to characterise metal–organic frameworks for adsorption applications
TL;DR: An overview of how molecular simulation can be used to characterise metal-organic frameworks for adsorption applications is provided and particular attention is drawn to how these insights can be combined to develop design principles for specific applications.
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Framework-catenation isomerism in metal-organic frameworks and its impact on hydrogen uptake.
Shengqian Ma,Daofeng Sun,Michael W. Ambrogio,Jacqueline A. Fillinger,Sean Parkin,Hong-Cai Zhou +5 more
TL;DR: A strategy to control framework-catenation in MOFs has been presented and contributions to hydrogen uptake from interpenetration and unsaturated metal centers have been resolved.
Journal ArticleDOI
Atomic and electronic structure of gold clusters: understanding flakes, cages and superatoms from simple concepts
TL;DR: This tutorial review attempts to describe the development in understanding the structures of bare and ligand-protected gold clusters over the past decade, based on selected density-functional-theory calculations.
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Polymerization reactions in porous coordination polymers
TL;DR: This review discusses promising approaches to multiple controls of polymer structures, analysis systems for low-dimensional polymer assemblies and the construction of PCP-polymer nanohybrids, which are strong enticements to researchers in the areas of inorganic, materials and polymer chemistry.