Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
Reads0
Chats0
TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
More filters
Journal ArticleDOI
Metal-organic frameworks for energy storage devices: Batteries and supercapacitors
Tahira Mehtab,Ghulam Yasin,Muhammad Arif,Muhammad Shakeel,Rashid Mustafa Korai,Muhammad Nadeem,Noor Muhammad,Xia Lu +7 more
TL;DR: In this paper, a brief review is carried out on recent development in the utilization of metal-organic framework based materials for rechargeable batteries and supercapacitors, which would be the prevailing guidance to the materials design and optimization for battery community and electrochemical energy storage applications.
Journal ArticleDOI
Opportunities and challenges of MOF-based membranes in gas separations
TL;DR: In this article, a review of experimental and computational studies both for thin-film MOF membranes and MOF/polymer composite membranes is presented, addressing opportunities and challenges related with use of MOF membrane for gas separations as well as giving directions on the requirements for employing these membranes in practical applications.
Journal ArticleDOI
Advancement of sorption-based heat transformation by a metal coating of highly-stable, hydrophilic aluminium fumarate MOF
Felix Jeremias,Felix Jeremias,Dominik Fröhlich,Dominik Fröhlich,Christoph Janiak,Stefan K. Henninger +5 more
TL;DR: In this article, a 300 μm thick polycrystalline, thermally well coupled and highly accessible coating of microporous aluminium fumarate was deposited on a metal substrate via the thermal gradient approach, and found to be stable for the first 4500 ad/desorption cycles with water vapour.
Journal ArticleDOI
Enhanced Hydrolytic Stability of Self-Assembling Alkylated Two-Dimensional Covalent Organic Frameworks
TL;DR: In this article, the stability and bulk properties of two-dimensional boronate ester-linked covalent organic frameworks (COFs) were investigated upon exposure to aqueous environments.
Journal ArticleDOI
Water and methanol adsorption on MOFs for cycling heat transformation processes
Felix Jeremias,Felix Jeremias,Dominik Fröhlich,Dominik Fröhlich,Christoph Janiak,Stefan K. Henninger +5 more
TL;DR: In this paper, the authors summarize current investigations, developments and possibilities of metal-organic frameworks (MOFs) compared to classical materials, while, at the same time, the variability of the building blocks allows for tuning of the microporosity and hydrophobic/hydrophilic design, depending on the specific application.
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.