Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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NMR study of localization and mobility of 1‐phenylethanol enantiomers in homochiral metal‐organic sorbent Zn2(bdc)(S‐lac)(dmf)
TL;DR: Structural features of localization of chiral isomers of 1‐phenylethanol and their mobility activation in homochiral metal‐organic sorbent showed that stabilization of S‐PhEtOH structure is more preferable than stabilization of [Zn2(bdc)(S‐lac)(dmf)]·R‐PhTOH structure.
Journal ArticleDOI
1D chain, 2D layer and trinuclear unit based 3D frameworks of indium(iii)-biphenyl carboxylate complexes
TL;DR: In this paper, four indium(III)-biphenyl carboxylate coordination complexes were synthesized under hydrothermal and solvothermal conditions and characterized by X-ray powder diffraction (PXRD), infrared spectroscopy and elemental analysis.
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Fabrication of Ce-doped MIL-100(Fe), its adsorption performance, and the mechanisms to adsorb phosphate from water
TL;DR: In this paper , the authors used the solvothermal method to prepare a novel Ce-doped MIL-100(Fe), which consisted of irregular polyhedrons in the size range of tens of micrometers.
Journal ArticleDOI
Noncovalently‐bonded 2D‐3D Metal‐organic Frameworks via Assembly of Zn(Ac)2 with 3, 5‐Dimethylpyrazole and Carboxylate Ligands
TL;DR: In this article, four zinc(II) complexes, namely, Zn(Hdmpz)2(L1)2 (1) (HdMPz = 3, 5-dimethylpyrazole, HL1 = trichloroacetic acid), Zn2(μ-dmptz)2, HdMPZ)2.2(HDmpz), 2(L3)2] (2) (HL2 = 2, 4-dichlorophenoxyacetic acids), [Zn 2(μ
Journal ArticleDOI
Influence of the metal salt on the self-assembly of isophthaloylbis-β-alanine and Cu(II) ion
Smaragda Lymperopoulou,Smaragda Lymperopoulou,Vassiliki N. Dokorou,Vassiliki N. Dokorou,Athanassios C. Tsipis,Peter G. Weidler,John C. Plakatouras,Annie K. Powell,George E. Kostakis +8 more
TL;DR: In this article, the initial employment of the new pseudopeptidic ligand isophthaloylbis-β-alanine (H2IBbA, H2L) with CuII ion affords a one dimensional (1D) [Cu2L2(H2O)(CH3OH)]·2H 2O·CH 3OH (1) and a two dimensional (2D)
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.