Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
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Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Two Interpenetrating 3D Networks Which Generate Spacious Sealed-Off Compartments Enclosing of the Order of 20 Solvent Molecules in the Structures of Zn(CN)(NO3)(tpt)2/3.cntdot.solv (tpt = 2,4,6-tri(4-pyridyl)-1,3,5-triazine, solv = .apprx.3/4C2H2Cl4.cntdot.3/4CH3OH or .apprx.3/2CHCl3.cntdot.1/3CH3OH)
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Photochemical synthesis and structure of a 3-dimensional anionic polymeric network of an iron(II) oxalato complex with tris(2,2'-bipyridine)iron(II) cations
TL;DR: In this article, the structures of single crystals of a 3-dimensional polymeric compound [Fe II (bipy) 3 ] 2+ n °Fe II 2 (ox) 3 ], where ox is oxalate and bipy is 2,2'-bipyridine, have been determined by X-ray diffraction.
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Accessing Postsynthetic Modification in a Series of Metal-Organic Frameworks and the Influence of Framework Topology on Reactivity
TL;DR: Two new metal-organic frameworks (MOFs) that have structures isoreticular to reported MOFs that use 1,4-benzenedicarboxylic acid (BDC) as a building block are constructed and NH(2)-BDC can be used as a surrogate for BDC in a number of MOFs thereby providing a handle for postsynthetic modification.
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Nanochannel-Promoted Polymerization of Substituted Acetylenes in Porous Coordination Polymers
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Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility
Aixiang Tian,Jun Ying,Jun Peng,Jingquan Sha,Zhangang Han,Jian-Fang Ma,Zhong-min Su,Ning-Hai Hu,Hengqing Jia +8 more
TL;DR: The structural analyses reveal that the length of flexible bis(triazole) ligands and metal ion coordination geometries have a synergic influence on the structures of this series of Wells-Dawson polyoxoanion-based hybrid compounds.