Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Influence of sterically non-hindering methyl groups on adsorption properties of two classical zinc and copper MOF types
TL;DR: The metal-organic frameworks (three-dimensional porous coordination polymers) as mentioned in this paper are representatives of the classical Zn-IRMOF series and Cu paddle-wheel complexes with H 2 Me 4 BPDC, where the dicarboxylate linker is a representative of the non-planar biphenyl ligand family.
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Synthesis and characterization of new oligomeric and polymeric complexes based on the [CuII(bpca)]+ unit [Hbpca = bis(2-pyridylcarbonyl)amine]
Lucia Carlucci,Gianfranco Ciani,Simona Maggini,Davide M. Proserpio,Roberta Sessoli,Federico Totti +5 more
TL;DR: In this paper, the bpca-based Cu(II) polynuclear coordination compounds [Hbpca=bis(2-pyridylcarbonyl)amine] were prepared using the [Cu(bpca)(H2O)2](NO3)·2H 2O (1) building block and characterized by single crystal X-ray diffraction.
Journal ArticleDOI
Bifunctional Chalcogen Linkers for the Stepwise Generation of Multimetallic Assemblies and Functionalized Nanoparticles
Jonathan A. Robson,Ferran Gonzàlez de Rivera,Ferran Gonzàlez de Rivera,Khairil A. Jantan,Margot N. Wenzel,Andrew J. P. White,Oriol Rossell,James D. E. T. Wilton-Ely +7 more
TL;DR: The disulfide ligand (SC6H4CO2H-4)2 acts as a simple but versatile linker for a range of group 8 transition metals through reaction of the oxygen donors.
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Metal–Organic Framework-Based Materials for Adsorption and Detection of Uranium(VI) from Aqueous Solution
TL;DR: In this paper , the progress on the research of MOF-based materials used for both adsorption and detection of uranium in water is first summarized, and then the authors discuss the challenges and perspectives of the MOFbased materials for uranium detection and containment.
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Simultaneous trace monitoring of prokinetic drugs in human plasma using magnetic dispersive micro-solid phase extraction based on a new graphene oxide/metal–organic framework-74/Fe 3 O 4 /polytyramine nanoporous composite in combination with HPLC
TL;DR: In this paper, a composite of GO/MOF-74/Fe3O4/polytyramine nanoporous composite was synthesized as a sustainable sorbent for magnetic dispersive micro-solid phase extraction (MD-µ-SPE) of prokinetic drugs.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.