Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
Reads0
Chats0
TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
More filters
Journal ArticleDOI
A Cu(ii)-MOF based on a propargyl carbamate-functionalized isophthalate ligand
Maria Cristina Cassani,Francesca Gambassi,Barbara Ballarin,Daniele Nanni,Ilaria Ragazzini,Davide Barreca,Chiara Maccato,Antonietta Guagliardi,Norberto Masciocchi,Alessandro Kovtun,Katia Rubini,Elisa Boanini +11 more
TL;DR: In this article, a copper-based metal-organic framework (MOF) was prepared using a new linker, a 5-substituted isophthalic acid bearing a propargyl carbamate group, intended to provide a terminal alkyne function protruding from the material surface.
Book ChapterDOI
Luminescent MOFs and Frameworks
TL;DR: In this article, the luminescence of metal-organic frameworks has evolved into a key property of these coordination compounds, and the large variability of suitable metals and ligands offers excellent options for ligand- and metal-based luminecence.
Journal ArticleDOI
Polycaprolactone/ZIF-8 nanocomposites fabricated for oil sorption and antibacterial applications
TL;DR: In this article, the mass ratio effects of ZIF-8 and polycaprolactone nanocomposites on the oil sorption efficiency and antibacterial activity were studied.
Journal ArticleDOI
New polynuclear compounds based on N-benzyliminodipropionic acid: solution studies, synthesis, and X-ray crystal structures
Emiliano Braña,Delfina Quiñone,Sebastián Martínez,Joaquín Grassi,Ignacio Carrera,Julia Torres,Javier González-Platas,Gustavo Seoane,Carlos Kremer,Carolina Mendoza +9 more
TL;DR: In this paper, three polynuclear compounds based on a dicarboxylic acid ligand are reported, and the structures of the dinuclear copper units are arranged in a rhombus type grid, in a 2D layer structure.
Journal ArticleDOI
A systematic study on the thermal decomposition reactions of coordination polymers based on metal(II) selenocyanates and 4,4′-bipyridine: Directed synthesis of a μ-1,3 bridging selenocyanate
Mario Wriedt,Christian Näther +1 more
TL;DR: In this paper, the reaction of manganese, iron, cobalt, and nickel (II) selenocyanate with 4,4′-bipyridine (bipy) in water at room temperature leads to the formation of the ligand-rich 1:2 hydrates [{M(bipY)(NCSe)2(H2O)2}·bipyi]n with MÕ=Mn (1-Mn), Fe(1-Fe), Co (2-Co), and Ni (1
References
More filters
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.