Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
Cobalt(II)-(dpyo)-dicarboxylate networks: unique H-bonded assembly and rare bridging mode of dpyo in one of them [dpyo = 4,4'-dipyridyl N,N'-dioxide].
TL;DR: The structural determination reveals 1 and 2 are covalent bonded 2D networks of 4,4 topology and of these, complex 2 undergoes a H-bonding scheme resulting in a 3D supramolecular architecture.
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Honeycombs, herringbones and brick-walls; three-fold guest-dependent variation in copper trimesate complexes bearing sulfimide ligands.
TL;DR: Key to the supramolecular isomerism observed is the ability of 1 to facilitate structural isomersism at copper(II) centres.
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Highly porous metal-organic framework containing a novel organosilicon linker--a promising material for hydrogen storage.
TL;DR: The potential field of H(2) inside PCN-12-Si was derived from the simulations and analyzed in detail, providing valuable insights concerning the preferred adsorption sites on an atomic scale.
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Infinite Chains of Quasi-Planar Hexameric Water Clusters Stabilized in a Metal-Organic Framework Built from CoII and Pyrazine- 2,3,5,6-tetracarboxylic Acid
TL;DR: In this article, a 3D structure of cyclic water hexamers has been proposed, which consists of two-dimensional sheets of metal-organic frameworks and infinite chains of cyclically water hexamerers that join these sheets to form an overall 3D structural structure.
Journal ArticleDOI
Syntheses, structures and properties of cadmium benzenedicarboxylate metal–organic frameworks
Andrew D. Burrows,Kevin Cassar,Tina Düren,Richard M. W. Friend,Mary F. Mahon,Sean P. Rigby,Teresa L. Savarese +6 more
TL;DR: Kinetic data indicate that the hysteresis is not due to mass transfer limitations, and the most likely explanation for this behaviour lies in partial collapse of the framework to an amorphous phase under the conditions of activation.