Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Luminescent Functional Metal–Organic Frameworks
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
TL;DR: A comparison study of 3D Networks Based on Polypyrazolates, Metal 1,2,4-Triazolate Frameworks, and Univalent Coinage-Metal Tetrazolate Framework 1025.
Journal ArticleDOI
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
References
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Journal ArticleDOI
MOFs as adsorbents for low temperature heating and cooling applications.
TL;DR: The 3D metal-organic framework (MOF) (3)(infinity) is found to be a reversibly dehydratable-hydratable water-stable MOF material with a large loading spread as a candidate for solid adsorbents in heat transformation cycles for refrigeration, heat pumping, and heat storage.
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Crystal engineering of binary metal imidazolate and triazolate frameworks.
Jie-Peng Zhang,Xiao-Ming Chen +1 more
TL;DR: This article summarizes the recent advances in the crystal growth, structural control strategies and diverse structures of the binary metal imidazolate and triazolate frameworks, which are the simplest systems for crystal engineering of two- and four-connected coordination polymers.
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Homo- and heterometallic coordination polymers from the f elements
TL;DR: In this article, the structural features and luminescent behavior of Lanthanide and actinide-based coordination polymers and metal-organic framework materials are discussed and compared.
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Design of MOFs and intellectual content in reticular chemistry: a personal view
TL;DR: A personal perspective on the ideas leading to the development of reticular chemistry and the feasibility of achieving targeted materials with predetermined metrics and functionality by designed synthesis is defended.
Journal ArticleDOI
Recent Advances in Luminescent Monomeric, Multinuclear, and Polymeric Zn(II) and Cd(II) Coordination Complexes
Shao-Liang Zheng,Xiao-Ming Chen +1 more
TL;DR: In this paper, Queisser et al. summarized recent progress on the luminescence studies of monomeric, multinuclear, and polymeric Zn(ii)/Cd(ii) coordination complexes, involving spectroscopic, photophysical, and photochemical studies, as well as molecular and electronic structural investigations, focussing mainly on the interplaying factors that govern luminescent origin of the lowest-lying emissive states.