Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Fluorescent silver nanoclusters (Ag NCs) in the metal–organic framework MIL-101(Fe) for the catalytic hydrogenation of 4-nitroaniline
TL;DR: In this article, a fluorescent Ag nanocluster deposited iron-based metal organic framework, Ag NC@MIL-101(Fe), has been synthesized by a solution impregnation method.
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Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(III) luminescent “half-helicates”
Christophe Lincheneau,Carole Destribats,Dawn E. Barry,Jonathan A. Kitchen,Robert D. Peacock,Thorfinnur Gunnlaugsson +5 more
TL;DR: The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH(3)CN give rise to the formation of lanthanide luminescent 'half-helicates' in 1 : 3 (Ln:ligand) stoichiometry; the formation was observed by monitoring the changes in the ground and the excited state properties of the ligands.
Journal ArticleDOI
2∞[Bi2Cl6(pyz)4]: a 2D-pyrazine coordination polymer as soft host lattice for the luminescence of the lanthanide ions Sm3+, Eu3+, Tb3+, and Dy3+.
TL;DR: The 2D-coordination polymer was synthesized from BiCl3 and a self-consuming melt of pyrazine and proves to be a suitable soft host lattice for in situ co-doping of the lanthanide ions Sm(3+), Eu( 3+), Tb(3 +), and Dy(3+) during network formation.
Journal ArticleDOI
Water-free neodymium 2,6-naphthalenedicarboxylates coordination complexes and their application as catalysts for isoprene polymerization.
TL;DR: A series of four coordination polymers based on neodymium have been hydrothermally synthesized with different carboxylic acids as a linker, affording cis-polyisoprene with good conversions.
Journal ArticleDOI
Synthesis of a 3D photochromic coordination polymer with an interpenetrating arrangement: crystal engineering for electron transfer between donor and acceptor units
TL;DR: In this article, a photochromic coordination network is constructed via the combination of viologen and carboxylate fragments, and close packing of the two-fold diamond-like interwoven mode creates electron transfer bridges for the acceptor and donor components.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.