Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
Citations
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Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer.
TL;DR: The nickel(II)/lead(II) coordination polymer complex has been synthesized and characterized and has been successfully applied in a technologically challenging thin-film photosensitive Schottky device.
Journal ArticleDOI
Synthesis of Iron Doped Zeolite Imidazolate Framework-8 and Its Remazol Deep Black RGB Dye Adsorption Ability
Mai Thi Thanh,Tran Vinh Thien,Vo Thi Thanh Chau,Pham Dinh Du,Nguyen Phi Hung,Dinh Quang Khieu +5 more
TL;DR: In this article, the removal of Remazol Deep Black (RDB) RGB dye from aqueous solutions was investigated and the various factors affecting adsorption such as pH, initial concentration, contact time, and temperature were investigated.
Journal ArticleDOI
Molecular tectonics: homochiral 3D cuboid coordination networks based on enantiomerically pure organic tectons and ZnSiF6
TL;DR: Upon combining enantiomerically pure bis-monodentate organic tectons with ZnSiF6, homochiral 3D cuboid architectures displaying chiral channels are formed.
Journal ArticleDOI
Supramolecular assemblies involving metal–organic ring interactions: heterometallic Cu(II)–Ln(III) two-dimensional coordination polymers
Konstantis F. Konidaris,Christine N. Morrison,John G. Servetas,Matti Haukka,Yanhua Lan,Annie K. Powell,John C. Plakatouras,George E. Kostakis +7 more
TL;DR: In this article, three isostructural two-dimensional coordination polymers of the general formula [Ln2(CuL)3(H2O)9]·5.5 H2O have been synthesized and isolated from aqueous solutions and their single-crystal structures determined by X-ray diffraction.
Journal ArticleDOI
Syntheses, structures and properties of group 12 element (Zn, Cd, Hg) coordination polymers with a mixed-functional phosphonate-biphenyl-carboxylate linker
Christian Heering,Biju Francis,Bahareh Nateghi,Gamall Makhloufi,Steffen Lüdeke,Christoph Janiak +5 more
TL;DR: In this article, the coordination behavior of the carboxy-phosphonate-carboxylate ligand was studied for the group 12 elements zinc, cadmium and mercury.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.