Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Cobalt(II) compounds with acetone isonicotinoyl hydrazone tautomers: Syntheses and crystal structures of complexes with free donor atoms
TL;DR: In this paper, the possibility of formation of cobalt(II) complexes with free N-donor atoms based on acetone isonicotinoyl hydrazone (Hisn), is verified.
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What can only occur in supramolecular systems; first solid-state conversion of micro to nanostructures without any treatment in environmental conditions.
TL;DR: In this paper, the sonochemical reaction between lead acetate and 5-chloro-8-hydroxyquinoline resulted in formation of one-dimensional pencil shaped [Pb2(5-Clq-8)-ol)2(OAc)2]n (1) supramolecular polymer microrods.
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Reversible Solvent-Exchange-Driven Transformations in Multifunctional Coordination Polymers Based on Copper-Containing Organosulfur Ligands
TL;DR: In this article, a series of coordination polymers based on copper with chloride or bromide and dipyrimidinedisulfide is reported, which reveal a rich structural variety as a result of the number of coordination modes available to the organosulfur ligand.
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Homochiral zinc benzene-1,3,5-tricarboxylate coordination networks with a chiral nitrogen ligand or template: Spontaneous resolution of a twofold interpenetrated 2D sql (4,4) network and formation of enantiopure 3D sra (SrAl2) networks
Anas Tahli,Anne-Christine Chamayou,Ümit Köc,Robin Brückner,Reda F.M. Elshaarawy,Reda F.M. Elshaarawy,Christian Heering,Christoph Janiak +7 more
TL;DR: In this paper, a pair of homochiral enantiomorphic two-fold interpenetrated mixed-ligand coordination polymers (CPs) were found in a racemic conglomerate in space group P212121 with enantiomorphous crystals by spontaneous resolution.
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Pre-organisation or a hydrogen bonding mismatch; silver(I) diamide ligand coordination polymers versus discrete metallo-macrocyclic assemblies
TL;DR: Abdul-Kadir, Clements, Lyall R. Hanton, Courtney A. Hollis, and Christopher J. Sumby as discussed by the authors have published a collection of essays on Islam.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.