Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Polythiophene hybrid film with zirconium–porphyrin metal–organic framework for improved charge carrier transport and NO2 gas sensing
TL;DR: In this paper , the electrical and physical properties of Fe porous coordination network 222 (PCN-222) and explored its potential as an analyte interacting material inserted into a polymer active layer.
Journal ArticleDOI
An original 3D coordination polymer constructed from trinuclear nodes and tetracarboxylato spacers
Alina S. Dinca,Andreea Dogaru,Adrian E. Ion,Adrian E. Ion,Simona Nica,Dan Dumitrescu,Sergiu Shova,Francesc Lloret,Miguel Julve,Marius Andruh +9 more
TL;DR: In this article, a 3D coordination polymer, ∞3[{Cu3(felden)4(btec)3]·17H2O, has been assembled using cationic trigonal nodes.
Journal ArticleDOI
Removal of Alizarin red S by calcium-terephthalate MOF synthesized from recycled PET-waste using Box-Behnken and Taguchi designs optimization approaches
TL;DR: In this article , the authors used the Box-Behnken (BBD) and Taguchi (Taguchi) models to optimize removal conditions of Alizarin red S (ARS) dye from an aqueous solution.
Dissertation
Adsorbent Particle Design for Application in Gas Adsorption Processes
TL;DR: In this article, aluminum terephthalate (MIL-53(Al) was shaped using two different methods: compression without binder (binderless) and extrusion with a binder.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.