Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
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TLDR
In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.Abstract:
This review (over 380 references) summarizes metal–organic frameworks (MOFs), Materials Institute Lavoisier (MILs), iso-reticular metal–organic frameworks (IR-MOFs), porous coordination networks (PCNs), zeolitic metal–organic frameworks (ZMOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.read more
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Application of MIL-100(Fe) in drug delivery and biomedicine
Christian Rafael Quijia,Camila de Lima,Caroline Silva,Renata Carolina Alves,Regina Célia Galvão Frem,Marlus Chorilli +5 more
TL;DR: In this paper, a review summarizes and discusses the recent advances in the synthesis of the micro and nano-MIL-100(Fe), the physicochemical stability concerning changes in pH, temperature, and physiological conditions, as well as biomedical applications such as biosensors, phototherapy, encapsulation methods, and drug release.
Journal ArticleDOI
Strain‐Induced Isomerization in One‐Dimensional Metal–Organic Chains
Mykola Telychko,Jie Su,Aurelio Gallardo,Aurelio Gallardo,Yanwei Gu,Jesús I. Mendieta-Moreno,Dongchen Qi,Anton Tadich,Shaotang Song,Pin Lyu,Zhizhan Qiu,Hanyan Fang,Ming Joo Koh,Jishan Wu,Pavel Jelínek,Jiong Lu +15 more
TL;DR: An internal strain-induced skeletal rearrangement of one-dimensional metal-organic chains (MOCs) via a concurrent atom shift and bond cleavage on Cu(111) at room temperature is reported.
Journal ArticleDOI
Influence of metal ion on structural motif in coordination polymers of the pseudopeptidic ligand terephthaloyl-bis-beta-alaninate
TL;DR: The combination of semiflexible terephthaloyl-bis-β-alaninate and metal ions at room temperature in aqueous solution results in the formation of five new compounds formulated as [Ca(TBbA)(H2O)3]· H2O (1), [Mn(TBa)(H 2O)2]·H2Os (2), [Co(TBba)(H&O)4]· 2H2OS (3), [Ni(TBboA)
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Organic-inorganic hybridization of isoreticular metal-organic framework-3 with melamine for efficiently reducing the fire risk of epoxy resin
TL;DR: In this paper, a novel organic-inorganic hybrid flame retardant denoted as IR-MOF-3-Mel was synthesized by covalent hybridization of isoreticular metal-organic framework-3 with melamine.
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Application of a new metal-organic framework of [Ni2F2(4,4'-bipy)2(H2O)2](VO3)2.8H2O as an efficient adsorbent for removal of Congo red dye using experimental design optimization.
TL;DR: The aim of this study is the introduction of a new metal-organic framework that can adsorb Congo red with high adsorption capacity and the synthesis of this framework as a high efficient adsorbent for Congo red removal.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.